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USA Water crisis: Bayou Corne and Grand Bayou sinkhole – Special water education edition part 2 of 3 History and video timeline – June 28, 2012 – May 16, 2013 – the facts about Grand Bayou sink hole.

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USA: Bayou Corne and Grand Bayou sinkhole history

USA Water crisis  Bayou Corne and Grand Bayou sinkhole

Grand Bayou sink hole history timeline.

Bubbles in Grand Bayou June of 2012 courtesy of WBRZRight click and click view image to enlarge

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Save the Water™ / Water Research / Water Education / Global Water News ©2013

Introduction: Part 2 of 3: Bayou Corne – Grand Bayou sinkhole series May 17, 2013 / Anthony Kozuh Research Director / STW™

Part two of this Save the Water™ special water education edition chronologically covers the history and timeline facts of the Bayou Corne – Grand Bayou sinkhole, beginning two months prior the actual collapse on August 3, 2012 until May 16, 2013. The videos within this report will assist you in visualizing the actual magnitude of this situation and I personally recommend to view these videos as pictures speak more than words. [ Click full screen: videos will be in high definition ]

Part three: 05/18/2013 will consist of scientific facts regarding sink holes, videos, and material to assist you in further research of the Bayou Corne – Grand Bayou environmental – water crisis. We wish to thank WBRZ , TheAdvocate.com and WWLTV.com for the detailed coverage they have provided since the outset of this water crisis.

Click Here For Lake Peigneur Part One: Video – Lake Peigneur could be worse than Assumption sinkhole
Click Here For Lake Peigneur Part Two: Largest man-made vortex – Lake Peigneur update – special report.
Click Here For Grand Bayou sinkhole begins Part One: Bayou Corne – Grand Bayou sinkhole begins – can it end?

The beginning: June 27,2012 – Bubbles in bayou raise concerns.

Jun 28, 2012 / Adrian Pittman / Education timeline courtesy of WBRZ..read more /see Video

PIERRE PART – Assumption Parish authorities are holding a meeting to discuss a natural gas leak causing bubbles in Bayou Corne and Grand Bayou.

For seven years, Shelly Hernandez has called Bayou Corne home. “I really love the area, it was very peaceful until we started having gas bubbling,” she said. For weeks now they’ve been blistering the surface of Bayou Corne and Grand Bayou, leaving residents living on these bayous concerned. “This is not an accident, this is something that’s been caused by someone,” said resident Randy Rousseau. But no one seems to know who. One thing parish officials do know is that the bubbles are caused by a natural gas leak. “It’s the fear of the unknown… we been seeing it, and wondered about it, and knew it wasn’t natural,” Rousseau said.

The parish Office of Homeland Security and Emergency Preparedness is investigating the leak. Officials say there’s no serious risk of it catching fire. “There’s been no readings to show flamability of the product coming from bubbles, as of right now, no water ways or any evacuations have happened,” said parish OHSEP Manager John Boudreaux. But Rousseau says he’s not waiting around for that to happen. “I have a house and business in Grand Bayou, I don’t live there anymore. I bought other property, my wife and I didn’t feel safe,” he said.

Residents living in Bayou Corne are on edge.

Jul 13, 2012/ Adrian Pittman / Education timeline courtesy of WBRZ..read more

BELLE ROSE- Residents living on Bayou Corne, in Assumption Parish, are living with fear, because of the uncertainty of a natural gas leaks, that’s boiling to the top of the bayou. Today, USGS will be installing seismic monitors in the area where the bubbles are appearing.

Gas bubbles continue in Bayou Corne.

Jul 18, 2012 / Education timeline courtesy of WBRZ..read more

NAPOLEONVILLE – Analysts pulled gas samples today from the bubbling Bayou Corne and Grand Bayou areas in their continuing search to find out what’s causing them. The Department of Environmental Quality and Department of Natural Resources have been in the area since July 14 trying to determine the source of the gas bubbles. A spokesperson said samples taken today were intended to validate samples the teams had already pulled from the area. The U. S. Geological Survey encouraged people living in the area to continue to report any tremors felt in the community to the Assumption Parish Office of Homeland Security and Emergency Preparedness, either online or by calling (985) 369-7386.

Abandoned well could be source of gas leak.

Jul 25, 2012 / Adrian Pittman / Education timeline courtesy of WBRZ..read more / Photos / Video

BELLE ROSE – Assumption Parish officials believe an abandon well leaking natural gas could be what’s causing bubbles on Bayou Corne and Grand Bayou.

A resident came across the abandoned well two days ago off La. 70, in a swamp near Bayou Corne. Officials said the well is leaking flammable natural gas, but the chance of any ignition is 35 percent. Although a lot of fingers point to this well as the cause for the bubbling bayou, officials still aren’t saying the mystery’s solved. “We have to check and try and determine what is the source of the gas that is bubbling in Bayou Corne and Grand Bayou, if this is related to one larger incident,” said Assumption Parish Emergency Preparedness manager John Boudreaux. Residents said at this point, they don’t know what to believe. “I’m not a scientist, I’m not an engineer, I don’t know any of this stuff, I’m just having to take people at their word for it. But we feel like we’re not getting enough real concrete answers to make us feel safe,” said Bucky Mistretta. Engineers plan to excavate around the well on Thursday to see if it really is the really problem.

Sinkhole appears in bubbling swamp.

Grand Bayou sinkhole 200 feet by 200 feet

Aug 3, 2012 / Russell Jones / Education timeline courtesy of WBRZ..read more

BAYOU CORNE – A sinkhole formed overnight in an area of Assumption Parish swamps that have been bubbling for several weeks now.

John Boudreaux, the director of the parish office of emergency preparedness, said the sinkhole measured about 200 feet by 200 feet and several trees had fallen into it. He said the sinkhole is on private land near the Texas Brine Co. LLC facility, near the areas of Bayou Corne and Grand Bayou which have been the site of unexplained gas bubbles for some time. Boudreaux said they will bring in a helicopter from Alexandria later today to get a better look at the sinkhole. Federal and state officials have been in the area searching for the cause of the bubbling and reported tremors in the area, but have not narrowed down a cause for the phenomena yet.

“Sinkhole” now “slurry area” in bayou.

Aug 3, 2012 / Russell Jones / Education timeline courtesy of WBRZ..read more

BAYOU CORNE – Parish officials are now calling what they initially said was a “sinkhole” a “slurry area” near bubbling bayous in Assumption Parish.

According to a press people in Bayou Corne reported a strong diesel smell this morning. Shortly after that authorities identified a “slurry area” where several trees had collapsed in a swamp area between Grand Bayou and Bayou Corne. State Police and parish emergency officials will fly over the site this afternoon to see if there are any other slurry areas. Other agencies will continue to monitor for any other slurry sites or expansion of the existing area. Bayou Corne and Grand Bayou have been the site of gas bubbling for the past few weeks, as well as tremors reported by people living in the area. So far no definite cause for the bubbling or tremors has been identified.

Officials say diesel found in liquefied swampland.

Aug 6, 2012 / Education timeline courtesy of WBRZ..read more

BATON ROUGE – State officials say preliminary slurry water samples pulled from the acre of swampland that liquefied into muck over the weekend indicate the presence of small amounts of diesel hydrocarbons.

The pond of muck, located in Assumption Parish, first appeared Friday night and grew quickly, bending a 36-inch natural gas pipeline buried 16 feet in the ground as the muck expanded. About 150 homes and several businesses were ordered to evacuate after Gov. Bobby Jindal declared a state of emergency for the parish when the slurry area appeared to be expanding. The Louisiana Department of Environmental Quality says it has not determined where diesel may be coming from. They plan to take more tests. Meanwhile parish officials say the size of the slurry hole has not changed since Sunday.

Hundreds evacuate while agencies monitor sinkhole.

Aug 6, 2012 / Adrian Pittman / Education timeline courtesy of WBRZ..read more

Assumption Parish Flyover 11/14/12

ASSUMPTION PARISH – Nearly 200 people left the Bayou Corne and Grand Bayou area after a sinkhole caused officials to order a mandatory evacuation.

The massive sinkhole, the size of a football field, is located about 2,000 feet behind Shelly Hernandez’s house. “We don’t know what’s going to happen. I feared this all along: something sinking, something blowing up,” Hernandez said. That concern has officials on high alert. Today diesel was found in the area, which officials believe is coming from an inactive cavern on the property of Texas Brine. The Houston-based company brought in geologists and geo-mechanical experts today to begin examining the inactive mine cavern, and see if it is the cause of the sinkhole and the mysterious natural gas bubbles recently found in the two bayous.

Parish officials are monitoring the area to make sure the diesel doesn’t reach a level where it could possibly ignite. “Air monitors that monitor the community have not shown any danger levels that would affect anything, but it is definitely there,” said emergency preparedness director John Boudreaux. But what’s behind all of this, is still up in the air. “Still fear of unknown,” said Hernandez, “because nobody knows anything.” Officials scheduled a community meeting Tuesday evening to brief the public about what they’ve found so far. The meeting is set for Aug. 7 at 6:30 p.m. at the St. Joseph the Worker Catholic Church Hall in Pierre Part, located on Highway 70. See Photos Video

Scientists to examine sinkhole.

Adrian Pittman: BAYOU CORNE – The company which owns land a massive sinkhole appeared on sent in experts today to see if they could connect it to bubbles that had been popping up in the nearby Assumption Parish bayous. A mandatory evacuation is still in affect for people living near Bayou Corne and Grand Bayou after the massive sinkhole was discovered. Parish officials are monitoring the area on Texas Brine’s 40-acre facility south of La. 70, and as of now it hasn’t grown. The Houston-based company is bringing in geologists and geo-mechanical experts today to begin examining an inactive salt mine cavern to see if it is the cause of the sinkhole and the mysterious natural gas bubbles recently found in the two bayous.

Meeting set to brief community on sinkhole

Aug 6, 2012 / Trey Schmaltz / Education timeline courtesy of WBRZ..read more

BAYOU CORNE- Assumption Parish, State, and facility owners will meet with people who live near a sinkhole that developed Friday. The sinkhole may be caused by a failure in a brine cavern inside a salt dome. The sinkhole is connected with some bubbles that appeared in Bayou Corne earlier this summer. The meeting is set for Tuesday, August 7, 2012, at 6:30 p.m. at the St. Joseph the Worker Catholic Church Hall in Pierre Part, located on Highway 70.

When the ground collapsed it also damaged a pipeline. Because of that, Highway 70 was closed- and remains closed- it may open overnight. The line is being depressurized. Friday night, people who live near the sinkhole were evacuated. A shelter at Belle Rose Middle School was opened.

State: salt dome, mining operation failure likely cause of sinkhole and bubbles

Trey Schmaltz: BATON ROUGE- State experts now think a failed salt dome, or mining operation, in Assumption Parish led to a sinkhole Friday and is also connected to a bubbling phenomenon in Bayou Corne as well as tremors in the area. “Through consultation with all the scientists involved, DNR has determined that the potential failure of a portion of an inactive salt-mining cavern near the area … is a likely cause of the occurrence and possibly the recent natural gas bubbling,” the state said in a news release late Friday.

The sinkhole developed sometime early Friday morning

The sinkhole developed sometime early Friday morning, a mandatory evacuation order was issued for the people who live near it about 16 hours later. “The Office of Conservation has issued an emergency order requiring a brine solution company to take steps to evaluate the structural integrity of one its inactive salt caverns,” the Louisiana Department of Natural Resources said. According to DNR, state leaders have been in contact with the company, and Texas Brine has “indicated that it intends to cooperate fully to evaluate the status of its cavern and take action to address any potential failure in structural integrity.” The bubbles are a natural gas mixture, and air monitoring is taking place. No unsafe air-related pollutants were found. The bubbles began about two months ago, followed by earthquakes, then the sinkhole on Friday. People in the area were asked to leave Friday night, a shelter was established at a school.

Cavern described.

Trey Schmaltz: BATON ROUGE- A representative for Texas Brine described what’s under Bayou Corne as a vase, where brine – a mixture of water and salt- is extracted from salt domes and used in various compounds. Under Bayou Corne, a cavern was created in a salt dome- nearly a mile under ground.

The operation was running for twenty years before it was shuttered three years ago. Now, a brine mixture fills the cavern where salt once formed. Company leaders aren’t sure what’s caused a sinkhole or bubbles in the area. But, Friday night, experts with the state blamed a possible failure in the salt dome. It had been described as a “stable formation” by a company representative, now they’re looking to see what issues, if any, there are with the cavern. The cavern is large enough to hold millions of barrels of the brine mixture. Texas Brine operates as many as four other similar operations in the Assumption Parish area- those are active.

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Natl. Guard reports sinkhole grew overnight.

Aug 9, 2012 / Russell Jones / Assumption Parish Police Jury /Education timeline courtesy of WBRZ..read more

BAYOU CORNE – Authorities in Assumption Parish reported that the slurry area near Bayou Corne grew overnight.

The National Guard took infared readings by helicopter overnight, and observed the sinkhole grew by 10 to 20 feet from north to south. Earlier today authorities said they were taking readings for naturally-ocurring radiation in the area of the sinkhole, which may have been left over from oil and gas exploration in the area. They said additional monitoring near bubbling areas of the bayou detected no radiation. A state Department of Environmental Quality Mobile Lab arrived on site today to check air quality levels in the Bayou Corne and Grand Bayou communities. A mandatory evacuation order for residents in the Bayou Corne community remains in effect. Click here for more updates from the Assumption Parish Police Jury’s blog about the sinkhole.

Residents near sinkhole voice relief well concerns

Aug 14, 2012 / Adrian Pittman / Education timeline courtesy of WBRZ..read more / PhotosVideo

ASSUMPTION PARISH – A company that owns an operation blamed for a massive sinkhole in Assumption Parish is expected to begin drilling an exploratory well by the end of the weekend.

The well drilled by Texas Brine LLC, will investigate a salt cavern experts believe is behind a massive sinkhole and mysterious bubbles in Bayou Corne. Neighbors are concerned about the risks that could come with drilling, including the possibility it could collapse the salt dome cavern. The nearest neighbor is about 25,000 feet from the site of the relief-well. Experts say at this point, they don’t anticipate risks but residents say they’re not taking any chances. “We’re going to have to leave. There’s too many ifs, and I can’t live with ifs. Because one of those ifs could put me on the other side of the grass,” says Duane Bier. Parts of the rig will start arriving tomorrow from Lafayette. The rig will be installed by layers, and once complete, it will be about 14 stories high.

Sinkhole swallows boat – workers rescued.

Aug 16, 2012/ Russell Jones / Education timeline courtesy of WBRZ..read more

BAYOU CORNE – Emergency personnel rescued two workers who were cleaning up a portion of the Assumption Parish sinkhole when their boat was caught in it.

The Assumption Parish Police Jury said the workers were on the southwest side of the sinkhole when 50 feet of land collapsed into it, trapping their boat. The workers had to be rescued by an airboat, and shortly afterward the boat they were originally in was swallowed by the sinkhole. Authorities said all workers have been accounted for and no injuries were reported. Cleanup operations near the sinkhole have been suspended as a precaution. Crews with Texas Brine LLC are building a drilling rig to get into a salt cavern near the sinkhole to learn more about what caused it. The sinkhole appeared more than a week ago and has continued to grow as land surrounding it breaks off into the slurry area. Health and environmental monitors in the area haven’t found any health threats from the sinkhole, or bubbling that continues in the surrounding bayous.

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Texas Brine offers residents checks.

Texas Brine Co. LLC suspended cleanup work at a large sinkhole in northern Assumption Parish after the southwestern edge of the slurry area collapsed Thursday morning, company and parish officials said.

Two workers with Texas Brine’s cleanup contractor, Clean Harbors of Norwell, Mass., were rescued from their small aluminum boat by a co-worker in an airboat shortly before the workers’ boat sank into the sinkhole along with the collapsing earth, the officials said. Assumption Parish Sheriff Mike Waguespack said the boat was tied to a leaning tree on the shoreline. The workers saw the tree begin to move and managed to get out the way, escaping with their equipment at about 8:30 a.m., the officials said.

Waguespack said an area of earth collapsed

that extended from the shoreline to about 50 feet inland. The sheriff said bubbling in the sinkhole intensified after the collapse. The sinkhole was discovered Aug. 3 about 200 feet from the well pad of a plugged and abandoned Texas Brine salt cavern in an area between Bayou Corne and Grand Bayou and south of La. 70 South. The collapse Thursday was on the well pad side of the sinkhole.

Louisiana Department of Natural Resources scientists suspect the cavern failed, released its brine contents and caused the sinkhole, which swallowed up forested swamps. A mandatory evacuation order has remained in place since the evening of Aug. 3 for the Bayou Corne and Grand Bayou areas. Parish officials have said the order affects about 150 residences.

DNR officials have ordered Texas Brine of Houston to drill a relief well to get a better understanding of what is happening with the cavern, a process that could take at least 40 days. Other developments also emerged from news statements Thursday and in recent interviews:

Texas Brine Co. LLC contractor Worley Catastrophe Response will begin distributing weekly housing assistance checks for $875 at 10:30 a.m. Friday at the Sheriff’s Office substation, 4024 La. 70 S., Pierre Part, to households affected by the evacuation order.

DNR and Louisiana Department of Environmental Quality officials said Thursday that a Crosstex Energy LP of Dallas salt cavern containing 940,000 barrels of liquid butane poses “little to no threat” to populations near the slurry hole.

Sonny Cranch, Texas Brine spokesman, said company officials expected that the edges of the sinkhole would continue gradually to fall in, or slough off, making the sinkhole bigger and shallower. In an updated estimate of the hole’s size Wednesday evening — before the Thursday collapse — state officials said the sinkhole was expanding at the edges, though still much smaller than the maximum size estimated by DNR scientists.

The statement said the sinkhole was 476 feet from the northeast to the southwest sides and 640 feet from the northwest to the southeast. “This natural growth of the sinkhole was expected and could continue,” the Wednesday statement said.

On Thursday after the collapse, Cranch said company officials will re-evaluate the sinkhole Monday to see if it has stabilized and will deploy more oil retardant boom. “But (workers) will not continue physical cleanup activities until they evaluate the sinkhole on Monday,” he said.

Workers with Clean Harbors have been collecting vegetation floating in the sinkhole in preparation for vacuuming diesel on the water’s surface. Cranch said the cleanup will move forward even though the sloughing process is continuing. “We’re not ready to abandon efforts to clean up the sinkhole at this time,” Cranch said. “We think that work can continue and continue safely as the sinkhole continues to stabilize.”

Despite the setback on cleanup, Cranch said the delivery of drilling rig parts to Texas Brine’s facility continued Thursday and assembly is underway. Drilling work could start late Friday or early Saturday, Cranch said. Worley Catastrophe Response, which will coordinate and manage the “Bayou Corne Incident Evacuee Fund” for Texas Brine, plans to issue checks to the representative of each household affected by the evacuation order, Texas Brine officials said.

The representative will have to display a Louisiana driver’s license or “other reasonably acceptable photo identification confirming residence in the evacuation zone,” company officials said in a news release. The original permit for the Texas Brine cavern requires the operator to provide assistance to residents in areas deemed to be at immediate potential risk, state officials have said. The requirement is triggered in the event of a sinkhole and evacuation, state officials said. Crosstex also submitted a revised worst-case scenario analysis in its risk management plan Wednesday at the request of DEQ Secretary Peggy Hatch. In a statement Thursday, DEQ officials noted that the cavern, which is a half-mile underground and far below the bottom of the sinkhole, cannot release its liquid butane contents without water being pumped into the cavern to push out the butane. The butane is also being held in the absence of oxygen.

“While it is easy to simply convert the known quantity of butane into a blast scenario, that does not mean this scenario is possible,” DEQ officials said in a statement. Crosstex’s other nearby cavern, which has the capacity to hold 1.7 million barrels, has no hydrocarbons inside and is filled with brine at present, company officials said in their letter. The sinkhole’s emergence followed more than two months of earth tremors and mysterious natural gas releases in Bayou Corne, Grand Bayou and water wells.

The gas bubbling has continued since the sinkhole emerged. Tremors ceased the day before the sinkhole was found. The Texas Brine salt cavern was carved out of the 1-mile by 3-mile Napoleonville Dome, a large underground salt deposit. The cavern, which was used to produce brine for industry and never for natural gas storage, was plugged and abandoned in June 2011 after company officials ran into trouble trying to expand the cavern.

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Cavern damaged – now crews have to figure out what happened.

Sep 25, 2012 / Trey Schmaltz / Education timeline courtesy of WBRZ..read more

BAYOU CORNE- Scientists discovered a salt brine cavern, deep under Assumption Parish, has been damaged. Seismic activity in the area is blamed.

The Louisiana Sinkhole Bugle

“The cavern damage was caused by an external source,” a spokesperson for Texas Brine said in a news release late Monday. Texas Brine operated a brine operation in the Bayou Corne/ Grand Bayou area years ago. Caverns were created inside a salt dome, deep underground to extract brine. In May, people began reporting tremors and bubbles in the bayous. Over the summer, ground subsided and created a sinkhole. Since then, crews have been trying to determine the cause- and what can be done to fix the situation.

“The tool used to measure cavern depth bottomed out at approximately 4,000 feet – a point estimated to be 1,300 feet higher than the floor had been measured prior to the cavern closure in 2011,” a representative of Texas Brine reported. “This preliminary finding indicates that some type of dense material has fallen to the bottom of the cavern. A sample of the material has been retrieved from the cavern floor and will be analyzed.” That material is described as abnormal, compared to what should be found in the sealed cavern. “Sonar inspection that is currently being conducted will provide a more detailed image of the cavern’s interior conditions and the possible source of the material at its base.” An entire community was evacuated, and still is not allowed to return.

Residents angry as Assumption sinkhole continues collapsing.

February 25, 2013 / wwltv.com / Katie Moore / Eyewitness News

Related: News articles WWLTV
Work halted at Assumption Parish sinkhole site
Assumption Parish sinkhole swallows another 25 trees
Jindal visiting sinkhole area for first time
State leaders say company has promised to negotiate buyouts over sinkhole
Jindal meets with parish officials over sinkhole, will visit next week
Work at Assumption sinkhole suspended after increase in seismic activity

BAYOU CORNE, La. — The Assumption Parish sinkhole is a lot like a living, breathing thing. More than 200 days after it mysteriously started swallowing up the swamp, hundreds of residents are still under a mandatory evacuation order.

Geophysicists say the cavern that caused the sinkhole at the surface is still collapsing, leaving Bayou Corne residents wondering if there will ever be an end in sight. Bayou Corne has always been a peaceful place. Spanish moss dangles from the trees and inlets that lead to Grand Bayou are intertwined with the streets like a braid. Most of the homes are situated with a bit of the bayou in their backyards, and that’s exactly why most residents called the area home.

We could drop the boat right there to go fishing

“We could drop the boat right there to go fishing. It was just like a paradise,” said former Bayou Corne resident Jamie Weber. Weber decided to move hear family out last fall. A sign on her old home says “Evaucated: Thank you Texas Brine.” She had no idea that she was putting her mobile home on land on top of an underground salt dome. The Napoleon Salt Dome is full of caverns that have been mined to make brine, or salt water. Other caverns on the dome have been used to store hazardous, potentially explosive gasses, like Butane.

Geophyisicists now say the western side of one of the brine caverns is collapsing, filling in from deep in the Earth, causing the sinkhole at the surface to expand and contract. “On Oct. 25, we moved out of our home when we finally found a rent house because they had put a vent well a hundred yards from my house,” Weber told a joint legislative committee at a hearing on the sinkhole at the State Capitol last week.

She and some of the 350 evacuated Bayou Corne residents packed the Baton Rouge hearing looking for answers. Many of the ones they keep getting are conflicting and confusing, especially from the state and the company that once mined the collapsing salt cavern Texas Brine. “The cause of the sinkhole is the subject of pending litigation. At this point, I don’t think it’s proper to have any discussion about what the cause is and whether we accept what anyone has said regarding the cause of the sinkhole,” Troy Charpentier, an attorney for Texas Brine, told the committee.

The secretary of the Louisiana Department of Natural Resources flat-out testified at the same hearing, “The cavern collapse led to the sinkhole and created a path for the natural gas to come to the surface.” But Secretary Stephen Chustz slipped out a backdoor, with his press secretary only offering an interview with himself after the hearing without giving us the chance to ask him any questions.

One of those questions: What caused the cavern to collapse?

“The sinkhole is constantly changing. It changes every time we go out there. Not just on the surface, but in the sub-surface,” said Gary Hecox, a hydrogeologist with CB&I, formerly the Shaw Group, who is a consultant for the state about how to best handle the sinkhole. He said it’s uncharted territory.

“The cavern was 3,400 feet deep, which is deeper than any known cavern failure impacting the surface in the international record,” Hecox said. Nowhere in the world has a brine cavern this large collapsed, and Hecox said the data shows it’s not finished yet. “We still have 450 feet to fill. How long is it gonna take to fill this up? At one foot per day, we’re still looking at an event that’s gonna run over a year,” he said.

Every time it shifts, recently installed seismic monitors pick up tremors like little earthquakes. When it does, big bubbles of natural gas, vegetation and crude oil are released to the surface. They call it a “burp”. “It appears that the sand and gravel that’s in the bottom of the sinkhole breaks up a large gas bubble into many small bubbles just like an aquarium,” Hecox continued, “That is a good thing. Because if you get a single bubble up and have an ignition source you can have a flash over.”

A flash over is an explosion, like the kind you can see if you leave the gas on too long before lighting a propane grill. But Hecox said a large natural gas bubble from the sinkhole lit by any ignition source could mean major damage on the surface. Instead those little bubbles are coming out all around the actual sinkhole site in the form of bubble sites in the bayou. Twenty new bubble sites have been spotted in the last month.

Nine months after the first ones surfaced, Texas Brine started installing vent wells to alleviate the pressure underground. A drive down Hwy. 70 will show you several of them burning around Bayou Corne. “We continue to install relief wells as fast as we can and will continue to do so as they continue to be effective,” said Bruce Martin, vice president of Texas Brine. But in recent weeks, some of the residents who stayed behind, and are living in the area at their own risk, noticed some problems that are typically invisible to the naked eye.

Bubble sites popped up in neighborhoods that are typically dry during flooding after a recent rain storm. It caused Wilma Subra, a chemist with the Louisiana Environmental Action Network, to raise a red flag with the Louisiana Department of Environmental Quality. “A house acts like a tent. So, if it’s migrating up through the soil, and it’s being caught in the house, it’s building up concentrations in the house. And then if it reaches explosive level, then one little spark in the house would set it off,” Subra said.

One of the residents who has stayed behind, Nick Romero, also testified before the legislative committee. He now has five DEQ monitors installed in his house to measure natural gas and other chemicals. “We have had our grand kids and now we can’t. I love to fish. And now I don’t want to,” he told the committee members, choking back tears. The residents are struggling not just with the instability underground, but in their lives.

“Once they told us that they wanted to put monitors in our house and that we’d have to live like, to me, like lab rats, to me, that was no way for my kids to grow,” Weber said. Many feel forgotten, Weber said. Especially by Gov. Bobby Jindal. The governor has yet to visit the sinkhole site or publicly talk about it.

“He’s promoting plants around the area, chemical plants. And he was in the area and he wouldn’t, still to this day does not acknowledge it,” Weber said. In October and November of 2012, Jindal announced two chemical plant expansions a few miles from Bayou Corne, one in nearby Geismar and one in Donaldsonville.

But in six months, he’s made no visit to the sinkhole site.

“Where is he? Where is Jindal? He’s all over the United States, but he can’t come forty minutes south of Baton Rouge and visit,” Weber asked. As photos from the Louisiana Environmental Action Network show, when the sinkhole first appeared, it was just 400 feet in diameter. As of mid-February, it had swallowed nine acres. Scientists say the worst-case scenario is it could swallow 40 acres.

Even if it does, many, like Weber, are now just hoping Texas Brine will buy them out so they can move on. The company told residents that they are working to stabilize the area before tackling buy outs because some residents are still hoping to return. Lawmakers are planning another joint hearing on the sinkhole March 18. Katie Moore / Email: kmoore@wwltv.com / Twitter: @katiecmoore

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Water still pouring through three breaches of Assumption sinkhole berm.

Western Berm Breach 5-10-13

High water driven by heavy rains poured inside a containment levee around the Assumption Parish sinkhole overnight Thursday and much of Friday, forcing workers to try to cut off the flow and to contain the hole’s brew of crude oil and brine.

Sinkhole MapRight click on image & click view to enlarge

Containment boom had not been laid out at that point, parish officials said. A second video shows the largest breach of all, about 75 feet across, with water levels nearly equalized between the swamps and inside the berm area, leaving an idle excavator sitting in shallow water.


Western Berm Breach 5-10-13 Part II

Because of problems going over wet clay on part of the berm’s southern leg, contractors worked Friday to finish the first phase of the V-shaped extension, or “bump out,” as a route to reach the largest breaches. But poor weather, including close lightning strikes, halted Texas Brine’s work Friday afternoon, Boudreaux said. The berm extension was nearly finished except for a small gap. “They can haul sand in the rain. I think their intention is to do that and finish the bump out and give good access to the bigger breaches,” he said.

Grand Bayou Flyover 5/14/13

Texas Brine Co. contractors plugged the final two breaches in a containment berm around the Assumption Parish sinkhole by early Tuesday after heavy rain and high water punched through the incomplete earthen barrier late last week, authorities said. With the holes plugged, Sonny Cranch, spokesman for Texas Brine, said workers resumed on Tuesday the previously planned work of building up the earthen levee surrounding the 71-acre area containing the sinkhole near the Bayou Corne community.

The Louisiana Sinkhole Bugle

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Water contamination news: EPA takes action against Buffalo area gas stations to protect ground water from petroleum contamination.

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Aug 14
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EPA Takes Action against Buffalo Area Gas Stations to  Protect Ground Water from Petroleum Contamination
Water contamination news:

EPA takes action against Buffalo area gas stations to protect ground water from petroleum contamination.

Contact: John Martin, (212) 637-3662, martin.johnj@epa.gov.

(New York, N.Y. – August 14, 2012) The U.S. Environmental Protection Agency has issued a legal complaint to the owners and operators of twenty-two underground storage tanks at gasoline stations in the Buffalo, New York area for violating various federal regulations dealing with ground water from petroleum contamination. The complaint, which seeks $582,803 in penalties, was issued to Amerimart Development Company, Inc., Qual-Econ Lease Co., Inc., Commercial Realty Fund II, MJG Enterprises Inc., and Clear Alternative of Western NY, Inc. (d.b.a. G & G Petroleum). These companies are either past or present owners or operators of gas stations in Buffalo, Amherst, and Tonawanda, N.Y. In addition to paying penalties, the complaint requires the facilities to all come into full compliance with the regulations.

“Gas station owners need to be vigilant in making sure that their petroleum storage tanks do not cause pollution,” said EPA Regional Administrator Judith A. Enck. “When underground tanks are not properly maintained, ground water can be contaminated, putting people and the environment at risk.”

Ground water is the source of drinking water for nearly half of all Americans. When petroleum or other hazardous substances leak from underground tanks, such leaks are difficult and expensive to clean, particularly if they involve a public source of drinking water.

The complaint alleges that one or more of the companies failed to:

Test the protection systems for two tanks and two fuel lines

Meet corrosion protection or other new standards for two tanks and seven fuel lines

Conduct release detection every thirty days on eleven tanks:

Perform annual tests of automatic line leak detector systems for nineteen underground storage tanks

Provide adequate equipment to protect against tank overfills for thirteen underground storage tanks

Conduct an annual line tightness test or conduct monthly monitoring of underground pressurized piping for seventeen fuel lines

Properly cap off two temporarily closed underground storage tanks

Keep adequate records of release detection monitoring for three facilities

Respond to a request for information for one facility

The law authorizes EPA to seek between $11,000 and $16,000 per tank for each day a violation exists.

For more information on proper maintenance of Underground Storage Tanks, visit:

gas tank contamination

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    Fracking – Injection wells – The hidden risks of pumping waste underground – An unseen link, then boom.

     waste injection wells, gas storage wells operate under similar principles and assumptions: that deeply buried layers of rock will prevent injected substances from leaking into water supplies,  News Postings Drinking water contamination news. Save our water  Volume 3


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     waste injection wells, gas storage wells operate under similar principles and assumptions: that deeply buried layers of rock will prevent injected substances from leaking into water supplies,  Drinking water contamination news

     

    Despite many successful water projects, billions of people still lack adequate water and sanitation
     
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    Fracking – Injection wells -An unseen leak, then boom.

    Firefighters continue to watch the flame go at what used to be Woody’s Appliance store in downtown Hutchinson on January 21, 2001 four days after an explosion rocked the city. (Photo by Fernando Salazar)

    by Abrahm Lustgarten, ProPublica, June 21, 2012, 10:01 a.m.

    On Jan. 17, 2001, Hutchinson, Kan., awoke to an apocalypse.

    Gas that had silently collected inside a downtown appliance store ignited, reducing two buildings to tinder carcasses and shattering windows for blocks.

    Three miles away, a geyser of gas shot out of the earth, sending mud and rocks 30 feet into the air. Elsewhere, the ground popped open like the rotten hull of a boat, spraying brown briny water or catching fire.

    The next morning, just when the earth seemed to recover its temper, a new plume of gas and water shot through the floor of a mobile home, killing two people. Hundreds of other Hutchinson residents were evacuated from their homes, many for months.

    The mysterious disaster claimed national headlines, but there was little public discussion of the fact that it was caused by problems with underground injection wells.

    Among a small community of geologists and regulators, however, the explosions in Hutchinson — which ranked among the worst injection-related accidents in history — exposed fundamental risks of underground leakage and prompted fresh doubts about the geological science of injection itself.

    Geologists in Hutchinson determined that the eruptions had sprung from an underground gas storage field seven miles away. For years, a local utility had injected natural gas between 600 and 900 feet down into old salt caverns, storing it in a rock layer believed to be airtight so that it could later be pumped back out and sold. The gas had leaked out and migrated miles into abandoned injection wells once used to mine salt, then shot to the surface.

    “It was an unusual event,” said Bill Bryson, a member of the Kansas Geological Survey and a former head of the Kansas Corporation Commission’s oil and gas conservation division. “Nobody really had a feeling that if there was a leak, it would travel seven miles and hit wells that were unknown.”

    Though regulated under different laws than waste injection wells, gas storage wells operate under similar principles and assumptions: that deeply buried layers of rock will prevent injected substances from leaking into water supplies or back to the surface.

    In this case the injected material had done everything that scientists usually describe as impossible: It migrated over a large distance, travelled upward through rock, reached the open air and then blew up.

    The case, described as “a continuing series of geologic surprises and unexpected complexities” by the Kansas Geological Survey, flummoxed some of the leading injection experts in the world.

    Perhaps more troubling was that some of the officials assumed to be most knowledgeable about injection wells and the risks of underground storage seemed oblivious to the conditions that led to the accident.

    “The existence of those widespread formations and old salt-solution wells was unknown to the operators of the storage facility, the Kansas State Geologic Survey, city personnel, and its inhabitants,” noted a 2006 paper authored by Sally Benson, a leading geoscientist at Lawrence Berkeley Lab’s earth sciences division, and others. “It is still not clear how long the leakage occurred.”

    Bryson agrees that officials should have known more about the number of abandoned wells in the area, but he says that otherwise Kansas’ regulations worked as intended.

    The cause of the accident was identified because workers were diligently monitoring pressure changes in the gas injection well, as they are required to do. Once in a while, accidents are going to happen, he said.

    “How far do you go to make sure that nothing will ever happen?” he said. “Lets face it: Something is going to go wrong… states have to be trusted enough to let us deal with that.”

    Facts: Ten scariest chemicals used in hydraulic fracking

     The following is courtousy of Michael Kelley | Mar. 16, 2012, 1:35 PM

    Methanol

    MethanolFlickr/prizepony
    Methanol appeared most often in hydraulic fracturing products (in terms of the number of compounds containing the chemical).
    Found in antifreeze, paint solvent and vehicle fuel.
    Vapors can cause eye irritation, headache and fatigue, and in high enough doses can be fatal. Swallowing may cause eye damage or death.
     
     

    BTEX compounds

    BTEX compoundsFlcikr/arimoore
    The BTEX compounds – benzene, toluene, xylene, and ethylbenzene – are listed as hazardous air pollutants in the Clean Air Act and contaminents in the Safe Drinking Water Act.
    Benzene, commonly found in gasoline, is also a known human carcinogen. Long time exposure can cause cancer, bone marrow failure, or leukemia. Short term effects include dizziness, weakness, headache, breathlessness, chest constriction, nausea, and vomiting. Toluene, ethylbenzene, and xylenes have harmful effects on the central nervous system. The hydraulic fracturing companies injected 11.4 million gallons of products containing at least one BTEX chemical between 2005 and 2009.

    Diesel fuel

    Diesel fuelA carcinogen listed as a hazardous air pollutant under the Clean Air Act and a contaminant in the Safe Drinking Water Act.
    In its 2004 report, the EPA stated that the “use of diesel fuel in fracturing fluids poses the greatest threat” to underground sources of drinking water.
    Hydraulic fracturing companies injected more than 30 million gallons of diesel fuel or hydraulic fracturing fluids containing diesel fuel in wells in 19 states.
    Diesel fuel contains toxic constituents, including BTEX compounds. Contact with skin may cause redness, itching, burning, severe skin damage and cancer. (Kerosene is also used. Found in jet and rocket fuel, the vapor can cause irritation of the eyes and nose, and ingestion can be fatal. Chronic exposure may cause drowsiness, convulsions, coma or death.)

    Lead

    LeadFlickr/matthileo
    A carcinogen found in paint, building construction materials and roofing joints.
    It is listed as a hazardous air pollutant in the Clean Air Act and a contaminant in the Safe Drinking Water Act.
    Lead is particularly harmful to children’s neurological development. It also can cause reproductive problems, high blood pressure, and nerve disorders in adults.
    One of the hydraulic fracturing companies used 780 gallons of a product containing lead between 2005 and 2009.

    Hydrogen fluoride

    Hydrogen fluorideFlickr/Molly Des Jardin
    Found in rust removers, aluminum brighteners and heavy duty cleaners.
    Listed as a hazardous air pollutant in the Clean Air Act.
    Fumes are highly irritating, corrosive, and poisonous. Repeated ingestion over time can lead to hardening of the bones, and contact with liquid can produce severe burns. A lethal dose is 1.5 grams.
    Absorption of substantial amounts of hydrogen fluoride by any route may be fatal.
    One of the hydraulic fracturing companies used 67,222 gallons of two products containing hydrogen fluoride in 2008 and 2009.

    Naphthalene

    NaphthaleneFlickr/CraftyGoat
    A carcinogen found in mothballs.
    Listed as a hazardous air pollutant in the Clean Air Act.
    Inhalation can cause respiratory tract irritation, nausea, vomiting, abdominal pain, fever or death.
     
     
     

    Sulfuric acid

    Sulfuric acidFlickr/yetanotherdave
    A carcinogen found in lead-acid batteries for cars.
    Corrosive to all body tissues. Inhalation may cause serious lung damage and contact with eyes can lead to a total loss of vision. The lethal dose is between 1 teaspoonful and one-half ounce.
     
     
     

    Crystalline silica

    Crystalline silicaSource: ProPublica
    A carcinogen found in concrete, brick mortar and construction sands.
    Dust is harmful if inhaled repeatedly over a long period of time and can lead to silicosis or cancer.
     
     
     
     

    Formaldehyde

    FormaldehydeFlickr/Stadtkatze
    A carcinogen found in embalming agents for human or animal remains.
    Ingestion of even one ounce of liquid can cause death. Exposure over a long period of time can cause lung damage and reproductive problems in women.
     
     
     

    Unknown chemicals

    Unknown chemicalsFlickr/SoulRider.222
    “Many of the hydraulic fracturing fluids contain chemical components that are listed as ‘proprietary’ or ‘trade secret.’ The companies used 94 million gallons of 279 products that contained at least one chemical or component that the manufacturers deemed proprietary or a trade secret. In many instances, the oil and gas service companies were unable to identify these ‘proprietary’ chemicals,suggesting that the companies are injecting fluids containing chemicals that they themselves cannot identify.”

     

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    Fracking
  • Within 100 years: Our underground drinking water could be filled with toxic waste
  • Fracking mines spread quickly in U.S. / Fracking by country data included
  • Michigan, Ohio should strengthen laws on fracking, says new NWF report
  • Methane migration probed in Tioga County
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    Water contamination education: Fracking defined – Animated and illustrated fracking news – Slickwater fracking, the technique now known for being so cheap yet so controversial.

     Horizontal drilling, hydraulic fracturing, and shale gas have received a ton of press lately Slickwater fracking the technique illustrated  Volume 3


    Slickwater fracking the technique illustrated Save the water current post

    News Posting
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    July 11
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    Feb 6 2013

     Horizontal drilling, hydraulic fracturing, and shale gas have received a ton of press lately,  Slickwater fracking, the technique illustrated

     

    Despite many successful water projects, billions of people still lack adequate water and sanitation
     
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    A Homeowner's Guide to Septic Systems A Homeowner’s Guide to Septic Systems:
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    Fracking slickwater fracking illustrated

    Animated fracking news-Slickwater fracking.

    This is the technological breakthrough that’s making people wildly bullish on America

    Written by Rob Wile @ Business Insider/ Follow Rob Wile on Twitter.* Copyright © 2012 Business Insider, Inc.

    This weekend, we told the story of three bears who are all bullish on America for one reason: Domestic oil and natural gas. In particular, Hugh Hendry fund manager for Scottish group Eclectica Asset Management, cited “the momentous nature of recent advances in shale oil and gas extraction.”

    So what are these great breakthroughs?

    As it turns out, the three great advances in shale resource extraction occurred more than a decade ago, according to Dan Steward, a geologist with Republic Energy and a former Vice President of Mitchell Energy.

    The first was horizontal well drilling, which infinitely expanded the potential uses of fracking (which has actually been around since the 1949*). Here’s an animation showing exactly what that looks like:

    The first commercially viable horizontal drills had already been executed in the 1980s.

    But it was not until the late ’90s that mapping technology was created that could determine where fracking would prove most successful.

    Microseismic technology (which were originally used to detect seismic activity around mines) involves lowering detectors into a listening well near a fracked well.

    Once the well has been drilled, the seismic devices pick up the noise of where the rocks are breaking, and triangulates the sounds to map out the rest of the play.

    Here’s an equally nifty animation that demonstrates microseismic mapping.

    The final development was the advent of slickwater fracking, the technique now known for being so cheap, yet so controversial.

    Slickwater fracks involve adding chemicals known as “friction reducers” to water to allow for more efficient gas extraction.According to Halliburton and Forest Oil Corp, slickwater fracks allow fluid to be pumped down the well-bore as fast as 100 barrels per minute. Without using slickwater the top speed of pumping is around 60 bbl/min. It also enables extraction in highly pressurized, deeper shales.

    In 1997, Mitchell Energy executed the first slickwater frack (.pdf). Steward says it cut down the cost of drilling a well from $375,000 to $85,000.

    The ensuing “natural gas revolution” has been more the result of revision after revision of potentially recoverable resources. For example, in 1999, a study estimated 8.4 trillion cubic feet of natural gas were recoverable in the mid-Atlantic Marcellus Shale. By 2006, that had been revised upward to 31.4. (Some some now argue we have reached a tipping point where has caused recoverability estimates to be revised back downward.)

    Here’s how that evolution has played out, according to data from Drilling Info:

    So the next time you read something about new innovations in shale extraction, remember this timeline, from Steward:

    “By the year 2000, Mitchell Energy had proven shale as a workable and viable. The energy industry recognized it, but financial markets didn’t recognize until 2002, and politicians only realized it in 2006.”

    It is these decade-old breakthroughs that have resulted in those cheap prices you keep hearing about.

    *Update June 6, 2012: The article originally stated fracking has been around since the 1920s — this should have referred to slanted drilling — a precursor to horizontal drilling — first recorded in 1929. Read more @ Business Insider, Inc

    Further reading:

    Slickwater / Fracking historical perspective

    By Theodore Gilliland, 04/19/2011
    Horizontal drilling, hydraulic fracturing, and shale gas have received a ton of press lately. But what impacts do these unconventional techniques have on energy markets?
    Neither hydraulic fracturing (fracking) nor horizontal drilling are new technologies—the first horizontal well was drilled in 1929 and Halliburton developed fracking in 1949.Shale gas extraction is even older—the first commercial well was drilled in 1821. However, when horizontal drilling and fracking were combined to drill in Texas’ Barnett Shale region in 2003, a natural gas boom was born. In the last decade, shale gas production has increased 14-fold.

    Exhibit 1: Historical Milestones in Unconventional Gas Drilling

    Fracking History

    Definitions by Wikimarcellus

    Slickwater fracking

    Slickwater or slick water fracturing is a method or system of hydro-fracturing which involves adding chemicals to water to increase the fluid flow. Fluid can be pumped down the well-bore as fast as 100 bbl/min. to fracture the shale. Without using slickwater the top speed of pumping is around 60 bbl/min.

    The process reportedly involves injecting friction reducers, usually a a polyacrylamide. Biocides, surfactants and scale inhibitors can also be in the fluid. Friction reducers speed the mixture. Biocides such as bromine prevent organisms from clogging the fissures and sliming things up downhole. Surfactants keep the sand suspended. Methanol and naphthalene can be used for biocides. Hydrochloric acid and ethylene glycol may be utilized as scale inhibitors. Butanol and ethylene glycol monobutyl ether (2-BE) are used in surfactants. Slickwater typically uses more water than earlier fracturing methods–between one and five million gallons per fracing operation.

    Other chemical compounds sometimes used include benzene, chromium and a host of others. Many of these are known to be toxic and have raised widespread concern about potential water contamination. This is especially true when the wells recieving slickwater hydro-fracturing are located near aquifers that are being tapped into for local drinking water. However, reports of actual drinking water contamination appear either very scarce or else non-existent. Hydro-fracturing activity is heavily regulated by state agencies.

    In summary, slickwater is a water-based fluid and proppant combination that has low-viscosity. Slickwater fracturing was first used in the Barnett shale. Mitchell Energy introduced the very first slickwater frac that utilized 800,000 gal. of water and 200,000 lbs. of sand as proppant. It is typically used in highly-pressurized, deeper shales, while fracturing fluids using nitrogen foam are more common in more shallow shales and those that have lower reservoir pressure.

    What is proppant?

    Proppant is porous material such as sand or ceramic beads that are used to prevent newly created fissures and fractures in the shale rock from closing up once it has been hydro-fractured.

    A typical hydro-fractured well uses between 300,000 and 500,000 lbs. of proppant.

    The objective of hydro-fracturing is to enhance the deliverability of trapped gas by making pathways for the flow of natural gas and other hydrocarbons from the shale reservoir to the wellbore. Two chief factors that influence the flow of gas are permeability and proppant.

    Stokes’ law can be used to define four variables that affect proppant settling velocity in a column of water:

    1. fluid specific gravity
    2. fluid viscosity
    3. proppant size
    4. proppant specific gravity

    The cost of hydro-fracturing can be minimized by by reducing frac fluid viscosity. According to Stokes law, reducing the particle (proppant) size in half cuts the settling rate by a factor of four. However, particle size is also proportional to the conductivity of a proppant pack. Hence, in designing a fracing plan these factors must be weighed against each other in order to optimize the flow of gas from the shale reservoir.

    Although naturally occurring sand is frequently utilized as proppant, specially engineered man-made proppants can be used too such as resin-coated sand or high-strength ceramic materials like sintered bauxite. Materials are carefully selected for size and sphericity to provide the most efficient conduit for production of gas and other hydrocarbons from reservoir to wellbore.

    There are three main types of proppant that are in use in hydro-fracturing. Listed in order of their unit cost, these include:

    • sand
    • sand coated with resin
    • ceramic proppant

    The higher initial cost of ceramic proppant over sand may be justified by higher returns on investment in terms of greater well production rates and total overall recovery of oil and gas from the well. Higher production rates result from the greater strength of ceramic proppant and its more uniform shape and size.

    Production engineers use fracture design models as a guide to optimizing fracturing by comparing treatment size versus fracture half-length. The purpose is to design a fracture stimulation plan that optimizes productivity. The lower the permeability of a reservoir the more fracture length determines the effectiveness of the stimulation. However, unless the fractures can be sustained unpropped, that is, unless the fracture length or height created by hydro-fracturing has residual conductivity without propping, it is a waste of fluid. That can reduce the return on investment of hydro-fracturing a well or even turn it into a loss situation.

    Facts: Ten scariest chemicals used in hydraulic fracking

     The following is courtousy of Michael Kelley | Mar. 16, 2012, 1:35 PM

    Methanol

    MethanolFlickr/prizepony
    Methanol appeared most often in hydraulic fracturing products (in terms of the number of compounds containing the chemical).
    Found in antifreeze, paint solvent and vehicle fuel.
    Vapors can cause eye irritation, headache and fatigue, and in high enough doses can be fatal. Swallowing may cause eye damage or death.
     
     

    BTEX compounds

    BTEX compoundsFlcikr/arimoore
    The BTEX compounds – benzene, toluene, xylene, and ethylbenzene – are listed as hazardous air pollutants in the Clean Air Act and contaminents in the Safe Drinking Water Act.
    Benzene, commonly found in gasoline, is also a known human carcinogen. Long time exposure can cause cancer, bone marrow failure, or leukemia. Short term effects include dizziness, weakness, headache, breathlessness, chest constriction, nausea, and vomiting. Toluene, ethylbenzene, and xylenes have harmful effects on the central nervous system. The hydraulic fracturing companies injected 11.4 million gallons of products containing at least one BTEX chemical between 2005 and 2009.

    Diesel fuel

    Diesel fuelA carcinogen listed as a hazardous air pollutant under the Clean Air Act and a contaminant in the Safe Drinking Water Act.
    In its 2004 report, the EPA stated that the “use of diesel fuel in fracturing fluids poses the greatest threat” to underground sources of drinking water.
    Hydraulic fracturing companies injected more than 30 million gallons of diesel fuel or hydraulic fracturing fluids containing diesel fuel in wells in 19 states.
    Diesel fuel contains toxic constituents, including BTEX compounds. Contact with skin may cause redness, itching, burning, severe skin damage and cancer. (Kerosene is also used. Found in jet and rocket fuel, the vapor can cause irritation of the eyes and nose, and ingestion can be fatal. Chronic exposure may cause drowsiness, convulsions, coma or death.)

    Lead

    LeadFlickr/matthileo
    A carcinogen found in paint, building construction materials and roofing joints.
    It is listed as a hazardous air pollutant in the Clean Air Act and a contaminant in the Safe Drinking Water Act.
    Lead is particularly harmful to children’s neurological development. It also can cause reproductive problems, high blood pressure, and nerve disorders in adults.
    One of the hydraulic fracturing companies used 780 gallons of a product containing lead between 2005 and 2009.

    Hydrogen fluoride

    Hydrogen fluorideFlickr/Molly Des Jardin
    Found in rust removers, aluminum brighteners and heavy duty cleaners.
    Listed as a hazardous air pollutant in the Clean Air Act.
    Fumes are highly irritating, corrosive, and poisonous. Repeated ingestion over time can lead to hardening of the bones, and contact with liquid can produce severe burns. A lethal dose is 1.5 grams.
    Absorption of substantial amounts of hydrogen fluoride by any route may be fatal.
    One of the hydraulic fracturing companies used 67,222 gallons of two products containing hydrogen fluoride in 2008 and 2009.

    Naphthalene

    NaphthaleneFlickr/CraftyGoat
    A carcinogen found in mothballs.
    Listed as a hazardous air pollutant in the Clean Air Act.
    Inhalation can cause respiratory tract irritation, nausea, vomiting, abdominal pain, fever or death.
     
     
     

    Sulfuric acid

    Sulfuric acidFlickr/yetanotherdave
    A carcinogen found in lead-acid batteries for cars.
    Corrosive to all body tissues. Inhalation may cause serious lung damage and contact with eyes can lead to a total loss of vision. The lethal dose is between 1 teaspoonful and one-half ounce.
     
     
     

    Crystalline silica

    Crystalline silicaSource: ProPublica
    A carcinogen found in concrete, brick mortar and construction sands.
    Dust is harmful if inhaled repeatedly over a long period of time and can lead to silicosis or cancer.
     
     
     
     

    Formaldehyde

    FormaldehydeFlickr/Stadtkatze
    A carcinogen found in embalming agents for human or animal remains.
    Ingestion of even one ounce of liquid can cause death. Exposure over a long period of time can cause lung damage and reproductive problems in women.
     
     
     

    Unknown chemicals

    Unknown chemicalsFlickr/SoulRider.222
    “Many of the hydraulic fracturing fluids contain chemical components that are listed as ‘proprietary’ or ‘trade secret.’ The companies used 94 million gallons of 279 products that contained at least one chemical or component that the manufacturers deemed proprietary or a trade secret. In many instances, the oil and gas service companies were unable to identify these ‘proprietary’ chemicals,suggesting that the companies are injecting fluids containing chemicals that they themselves cannot identify.”

     

    Facts: List of chemicals now known to be used in fracking

     
    Multiple names for the same chemical can also leave you with the impression that there are more chemicals than actually exist. If you search the National Institute of Standards and Technology (NIST) ‡ website the alternate names of chemicals are listed.

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    Chemical Name CAS Chemical Purpose Product Function
    Hydrochloric Acid 007647-01-0 Helps dissolve minerals and initiate cracks in the rock Acid
    Glutaraldehyde 000111-30-8 Eliminates bacteria in the water that produces corrosive by-products Biocide
    Quaternary Ammonium Chloride 012125-02-9 Eliminates bacteria in the water that produces corrosive by-products Biocide
    Quaternary Ammonium Chloride 061789-71-1 Eliminates bacteria in the water that produces corrosive by-products Biocide
    Tetrakis Hydroxymethyl-Phosphonium Sulfate 055566-30-8 Eliminates bacteria in the water that produces corrosive by-products Biocide
    Ammonium Persulfate 007727-54-0 Allows a delayed break down of the gel Breaker
    Sodium Chloride 007647-14-5 Product Stabilizer Breaker
    Magnesium Peroxide 014452-57-4 Allows a delayed break down the gel Breaker
    Magnesium Oxide 001309-48-4 Allows a delayed break down the gel Breaker
    Calcium Chloride 010043-52-4 Product Stabilizer Breaker
    Choline Chloride 000067-48-1 Prevents clays from swelling or shifting Clay Stabilizer
    Tetramethyl ammonium chloride 000075-57-0 Prevents clays from swelling or shifting Clay Stabilizer
    Sodium Chloride 007647-14-5 Prevents clays from swelling or shifting Clay Stabilizer
    Isopropanol 000067-63-0 Product stabilizer and / or winterizing agent Corrosion Inhibitor
    Methanol 000067-56-1 Product stabilizer and / or winterizing agent Corrosion Inhibitor
    Formic Acid 000064-18-6 Prevents the corrosion of the pipe Corrosion Inhibitor
    Acetaldehyde 000075-07-0 Prevents the corrosion of the pipe Corrosion Inhibitor
    Petroleum Distillate 064741-85-1 Carrier fluid for borate or zirconate crosslinker Crosslinker
    Hydrotreated Light Petroleum Distillate 064742-47-8 Carrier fluid for borate or zirconate crosslinker Crosslinker
    Potassium Metaborate 013709-94-9 Maintains fluid viscosity as temperature increases Crosslinker
    Triethanolamine Zirconate 101033-44-7 Maintains fluid viscosity as temperature increases Crosslinker
    Sodium Tetraborate 001303-96-4 Maintains fluid viscosity as temperature increases Crosslinker
    Boric Acid 001333-73-9 Maintains fluid viscosity as temperature increases Crosslinker
    Zirconium Complex 113184-20-6 Maintains fluid viscosity as temperature increases Crosslinker
    Borate Salts N/A Maintains fluid viscosity as temperature increases Crosslinker
    Ethylene Glycol 000107-21-1 Product stabilizer and / or winterizing agent. Crosslinker
    Methanol 000067-56-1 Product stabilizer and / or winterizing agent. Crosslinker
    Polyacrylamide 009003-05-8 “Slicks” the water to minimize friction Friction Reducer
    Petroleum Distillate 064741-85-1 Carrier fluid for polyacrylamide friction reducer Friction Reducer
    Hydrotreated Light Petroleum Distillate 064742-47-8 Carrier fluid for polyacrylamide friction reducer Friction Reducer
    Methanol 000067-56-1 Product stabilizer and / or winterizing agent. Friction Reducer
    Ethylene Glycol 000107-21-1 Product stabilizer and / or winterizing agent. Friction Reducer
    Guar Gum 009000-30-0 Thickens the water in order to suspend the sand Gelling Agent
    Petroleum Distillate 064741-85-1 Carrier fluid for guar gum in liquid gels Gelling Agent
    Hydrotreated Light Petroleum Distillate 064742-47-8 Carrier fluid for guar gum in liquid gels Gelling Agent
    Methanol 000067-56-1 Product stabilizer and / or winterizing agent. Gelling Agent
    Polysaccharide Blend 068130-15-4 Thickens the water in order to suspend the sand Gelling Agent
    Ethylene Glycol 000107-21-1 Product stabilizer and / or winterizing agent. Gelling Agent
    Citric Acid 000077-92-9 Prevents precipitation of metal oxides Iron Control
    Acetic Acid 000064-19-7 Prevents precipitation of metal oxides Iron Control
    Thioglycolic Acid 000068-11-1 Prevents precipitation of metal oxides Iron Control
    Sodium Erythorbate 006381-77-7 Prevents precipitation of metal oxides Iron Control
    Lauryl Sulfate 000151-21-3 Used to prevent the formation of emulsions in the fracture fluid Non-Emulsifier
    Isopropanol 000067-63-0 Product stabilizer and / or winterizing agent. Non-Emulsifier
    Ethylene Glycol 000107-21-1 Product stabilizer and / or winterizing agent. Non-Emulsifier
    Sodium Hydroxide 001310-73-2 Adjusts the pH of fluid to maintains the effectiveness of other components, such as crosslinkers pH Adjusting Agent
    Potassium Hydroxide 001310-58-3 Adjusts the pH of fluid to maintains the effectiveness of other components, such as crosslinkers pH Adjusting Agent
    Acetic Acid 000064-19-7 Adjusts the pH of fluid to maintains the effectiveness of other components, such as crosslinkers pH Adjusting Agent
    Sodium Carbonate 000497-19-8 Adjusts the pH of fluid to maintains the effectiveness of other components, such as crosslinkers pH Adjusting Agent
    Potassium Carbonate 000584-08-7 Adjusts the pH of fluid to maintains the effectiveness of other components, such as crosslinkers pH Adjusting Agent
    Copolymer of Acrylamide and Sodium Acrylate 025987-30-8 Prevents scale deposits in the pipe Scale Inhibitor
    Sodium Polycarboxylate N/A Prevents scale deposits in the pipe Scale Inhibitor
    Phosphonic Acid Salt N/A Prevents scale deposits in the pipe Scale Inhibitor
    Lauryl Sulfate 000151-21-3 Used to increase the viscosity of the fracture fluid Surfactant
    Ethanol 000064-17-5 Product stabilizer and / or winterizing agent. Surfactant
    Naphthalene 000091-20-3 Carrier fluid for the active surfactant ingredients Surfactant
    Methanol 000067-56-1 Product stabilizer and / or winterizing agent. Surfactant
    Isopropyl Alcohol 000067-63-0 Product stabilizer and / or winterizing agent. Surfactant
    2-Butoxyethanol 000111-76-2 Product stabilizer Surfactant

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    Fracking
  • Within 100 years: Our underground drinking water could be filled with toxic waste
  • Fracking mines spread quickly in U.S. / Fracking by country data included
  • Michigan, Ohio should strengthen laws on fracking, says new NWF report
  • Methane migration probed in Tioga County
  • What are the ten scariest chemicals used in fracking?
  • The Frick and Frac about hydraulic fracturing
  • Toxipedia: Hydraulic fracturing update
  • Drinking Water Contamination
  • Camp Lejeune news: Effects of drinking water contamination due to tetrachloroethylene.
  • Drinking water contamination: Tap water disinfectants linked to birth defects.
  • Camp Lejeune toxic water investigation. The families and protectors of the United States health in jeopardy .
  • High Arsenic in 1 in 5 New Hampshire Wells
  • Toxic garden hose water: Drinking from common water hoses potentially dangerous
  • India,West Mambalam: Overflowing sewage remains a perennial problem
  • Alberta Canada: 3,000 barrels of oil spilled from pipeline. Water OK after Canadian oil spill
  • Pesticides detected upstream of reservoir feeding Australia, Melbourne’s drinking water supply
  • Good News
  • Mayors make ‘Declaration on Water Sustainability’ to protect Great Lakes and St. Lawrence
  • Bio filters from tree fungi. Students research synthetic variant enzymes that can break down estrogen
  • Education Program
  • What are the facts about chloramines
  • Wastewater and antibiotic resistance
  • Sustainable denim manufacturing process creates ‘green’ jeans
  • India water crisis news: Delhi’s Lutyens’ zone reels under severe water crisis
  • Groundwater & aquifers, what they are and why they must be protected.
  • What are some bottle water facts? [Illustrated ]
  • Illustrated water cycle: Marine debris bulletin: Identifying high pressure “gas cylinders from Japan debris”
  • Archived Topics
  • Drinking Water Fears After Chemical Spill In North Bay
  • North Bay Ontario/Residents Evacuated, Driver Dead, In Contamination Rollover On Highway 63
  • Canadian B.C. Water Crisis Issues
  • Jamaica: No need to panic! Asbestos cement pipes safe, says NWC
  • Should We Hide Low-Dose Radiation Exposures From The Public?
  • Formaldehyde Pollution Disrupts Water Supplies in Eastern Japan
  • Chemicals In The Water: Problems and Solutions
  • What Is Hydraulic Fracturing Water Usage?
  • What chemicals are used in fracking? Part I
  • Whats Fracking All About? Part 2
  • Study has has raised concerns about the safety of gas drilling in the Marcellus Shale
  • Fracking: Natural Gas Fracking Fizzles in Michigan / Includes an EPA Fracking Directory
    Fluoride
  • Where can you get all the facts about fluoride contamination?
  • Fluoride News In America [Aspen Times] & [KREX News Room]
  • What do you need to know about chloramine-treated water?
  • What Are The True Facts About Fluoride And Your Health?
  • Chemical Spill: Formaldehyde 101: What Are The Facts?
  • “How Dangerous Is The Chemical Formaldehyde ?”
  • What Are The Facts About (Bisphenol-A) / BPA, Water And Health Risks?
  • What are some of the known water pollutants?
  • What Are Some Facts About Water? Over 100 Facts You May Not Know.
  • Savethewater Water Research and Education

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