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Ontario, Canada water contamination news: Lake Huron – Impact of diesel spill on water, environment: ‘Time will tell’

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News Brief
Vol.III
No.207
July 24
2012

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By Jim Bloch / Voice Reporter
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Great Lakes Water Pollution Lake HuronCanada water contamination news: Lake Huron – Impact of diesel spill on water, environment: ‘Time will tell’

Published: Monday, July 23, 2012/ By Jim Bloch / Voice Reporter

Lt. Justin Westmiller, of Marysville, public affairs officer of the U.S. Coast Guard, with a section of absorbent boom used to collect spill product. Containment booms, on the other hand, are generally yellow and much thicker; they’re used to keep a spill corralled.

How will Thursday’s diesel fuel spill into lower Lake Huron impact drinking water and the environment? The bad news is that diesel fuel is one of the most toxic forms of oil to marine life. The good news is that it evaporates quickly and is relatively easily dispersed in open water.

That’s the word from the National Oceanic and Atmospheric Administration, in a fact sheet on small diesel spills – 500-5,000 gallons – into natural water systems.

When the dredge barge Arthur J and the tug Madison capsized in Lake Huron, about two miles east of Lakeport State Park in rough water in the pre-dawn hours of July 19, the barge carried between 1,500-2,000 gallons of diesel fuel. Lt. Justin Westmiller, public affairs officer for the U.S. Coast Guard, did not want to classify the severity of the spill.

“At this point, we’re working on determining how much product made it into the water,” Westmiller said on Friday. He said it would be a couple of days before the amount of the release is known. Marine Pollution Control of Detroit, hired by the owner of the downed craft, MCM Marine of Sault Ste, arrived on the scene late Thursday. Divers from the company managed to the shut the remaining vents and all the valves on the Arthur J.

“We believe the leak is secure,” Westmiller said. “We’re continually assessing that. The situation is fluid out there.”

“Diesel fuel is light and volatile,” said Patty Troy, who runs the laboratory for the Port Huron Wastewater Treatment Plant and is the U.S. co-chair of the Binational Public Advisory Committee on the St. Clair River Area of Concern, charged with working to clean up the river. “It should dissipate without much action. Time will tell.”

“Two days ago, with 100 degree temperatures and the sun out, it would have dissipated quickly,” said Jeff Friedland, director of St. Clair County Emergency Management. The cleanup is occurring on a number of levels. One of the functions of the county hazmat team, Friedland explained, was decontaminating boats, personal floatation devices and other equipment exposed to the diesel fuel. Westmiller expected Marine Pollution Control to be on the scene until the salvage operation is complete.

By Thursday evening, the sheen of diesel fuel had expanded to a mile by two miles and reached the beach at the day use area of Lakeport State Park.

“We did have some diesel fuel sheening come ashore, but no heavy product,” said Westmiller. “That’s an important distinction. Sheen is normally unrecoverable.”

In other words, absorbent booms and other techniques would be unable to collect it. As of Friday morning, the public beaches at Metcalf Road, Fort Gratiot County Park and the beach at the day use area of Lakeport State Park, all on Lake Huron, were closed, said Kristine Morris, public information officer for St. Clair County. All other public beaches on the lake and the St. Clair River were open – with the exception of Chrysler Beach in Marysville, which the county health department closed at 4:30 p.m. on July 19 due to high e coli counts, unrelated to the diesel spill.

“Diesel oil is not very sticky or viscous, compared to black oils,” the NOAA fact sheet stated. “When small spills do strand on the shoreline, the oil tends to penetrate porous sediments quickly, but also to be washed off by waves and tidal flushing. Thus, shoreline cleanup is usually not needed. Diesel oil is readily and completely degraded by naturally occurring microbes, under timeframes of one to two months.”

NOAA reported that fish, invertebrates and seaweed can die if they come into contact with diesel. But because of the rapid dilution of small diesel spills in open water, no fish kills have ever been reported.

Why did the boats sink?

“It’s all under investigation,” said Westmiller, adding that it would probably be months before a final conclusion is reached.

“A lot of this is still unfolding,” said Troy. “As of (Thursday) afternoon, the water intake in Lambton, Ontario, remained closed. I’m confident that the water system was safe. All of the water plants were notified and all of the plants have many hours of capacity – they can shut down their intakes and still serve their customers for many hours. The fortunate thing was that officials learned of the spill and could respond to it before something bad happened. I’m grateful for that.”

Jim Bloch is a freelance writer. Contact him at bloch.jim@gmail.com.

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    Water pollution news: Deepwater Horizon oil spill disaster update – Oil from Deepwater Horizon disaster enters food chain in the Gulf of Mexico.

     Deepwater Horizon disaster, worst environmental  Disaster   Oil from Deepwater Horizon Disaster Entered Food Chain in the Gulf of Mexico

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    Horizon Oil Spill update

    Deepwater Horizon Disaster: BP nearing billion pound settlement with US authorities.

    Posted: 15/07/2012 16:38 / huffingtonpost.co.uk / Press Association

    Oil giant BP is reportedly nearing a £7.4 billion settlement with US authorities as it seeks to draw a line under the Deepwater Horizon disaster.

    The group hopes to unveil a deal with the US Department of Justice by September that would resolve all criminal and civil penalties, removing the spectre of a lengthy and costly legal battle, according to The Sunday Times. It has already provided 37 billion US dollars (£23.8 billion) to cover many of the costs following the disaster, which killed 11 workers in April 2010 and unleashed the biggest oil spill in American history.

    But this figure includes just 3.5 billion (£2.2 billion) to cover charges under the Clean Water Act, which could rise to up to 17.5 billion US dollars (£11.2 billion) if BP is found grossly negligent. It is thought BP is looking for a “grand settlement” of 15 billion US dollars covering Clean Water Act fines plus potential criminal charges and other damages.

    That would mean it has to find a further 11.5 billion US dollars (£7.4 billion).

    The Obama administration, which is keen to use the settlement as a potential vote winner ahead of the presidential election, is understood to be pushing for 25 billion US dollars (£16 billion) but both sides are thought keen to reach an agreement. A deal would be seen as a coup for chief executive Bob Dudley, who is under pressure to revive the company’s fortunes. Its shares are still a third lower than before the disaster.

    BP is aiming to sell up to 14 billion US dollars (£9 billion) in assets by the end of this year to complete its money raising programme.

    It’s been more than two years since one of the worst environmental disasters in US history. The images from the oil spill capture the horror of the event: take a look at 35 photos that will bring back memories at bottom of these articles.

    Related News On Huffington Post:

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    BP’s top bosses contended with screaming environmental protesters, a backlash on executive pay and more anger over the company’s record in the Gulf of Mexico…

    Science News

    … from universities, journals, and other research organizations

    Water Environmental Disaster news: Oil from Deepwater Horizon disaster entered food chain in the Gulf of Mexico

    ScienceDaily (Mar. 20, 2012) — Since the explosion on the BP Deepwater Horizon drilling rig in the Gulf of Mexico on April 20, 2010, scientists have been working to understand the impact that this disaster has had on the environment. For months, crude oil gushed into the water at a rate of approximately 53,000 barrels per day before the well was capped on July 15, 2010. A new study confirms that oil from the Macondo well made it into the ocean’s food chain through the tiniest of organisms, zooplankton.

    Reference

    Tiny drifting animals in the ocean, zooplanktons are useful to track oil-derived pollution. They serve as food for baby fish and shrimp and act as conduits for the movement of oil contamination and pollutants into the food chain. The study confirms that not only did oil affect the ecosystem in the Gulf during the blowout, but it was still entering the food web after the well was capped.

    Oil, which is a complex mixture of hydrocarbons and other chemicals, contains polycyclic aromatic hydrocarbons (PAHs), which can be used to fingerprint oil and determine its provenance. The researchers were able to identify the signature unique to the Deep Water Horizon well in the Gulf of Mexico.

    “Our research helped to determine a ‘fingerprint’ of the Deepwater Horizon spill — something that other researchers interested the spill may be able to use,” said Dr. Siddhartha Mitra of Eastern Carolina University. “Furthermore, our work demonstrated that zooplankton in the Northern Gulf of Mexico accumulated toxic compounds derived from the Macondo well.”

    The team’s research indicates that the fingerprint of the Deepwater Horizon oil spill could be found in some zooplankton in the Gulf of Mexico ecosystem at low levels, as much as a month after the leaking wellhead was capped. In addition, the extent of the contamination seemed to be patchy. Some zooplankton at certain locations far removed from the spill showed evidence of contamination, whereas zooplankton in other locations, sometimes near the spill, showed lower indications of exposure to the oil-derived pollutants.

    “Traces of oil in the zooplankton prove that they had contact with the oil and the likelihood that oil compounds may be working their way up the food chain,” said Dr. Michael Roman of the University of Maryland Center for Environmental Science.

    The study was led by East Carolina University with researchers from the University of Maryland Center for Environmental Science, Oregon State University, Georgia Institute of Technology, and U.S. Geological Survey. The paper, “Macondo-1 well oil-derived polycyclic aromatic hydrocarbons in mesozooplankton from the northern Gulf of Mexico,” was published in the February issue of Geographical Research Letters.

    Related Stories


    Deepwater Horizon Disaster Could Have Billion Dollar Impact

    (Feb. 17, 2012) — The Deepwater Horizon oil spill in the Gulf of Mexico in April 2010 will have a large economic impact on the US Gulf fisheries. A new study says that over seven years this oil spill could have a … read more

    Where Has All the Gulf Spill Oil Gone? (Feb. 1, 2011) — Many questions remain about the fate and environmental impact of the marine oil caused by the massive spill in the Gulf of Mexico from the Deepwater Horizon oil spill offshore drilling read more

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    Story Source:
    The above story Water Environmental Disaster news: Oil from Deepwater Horizon Disaster Entered Food Chain in the Gulf of Mexico is reprinted from materials provided by University of Maryland Center for Environmental Science.
    Note: Materials may be edited for content and length. For further information, please contact the source cited above.

    Save the Water™ Visits the Horizon Oil Spill

    After submitting various Save the Water™ (STW™) proposals to BP and the U.S. Coast Guard, Frank Ramos, president and CEO of STW™ and Pedro Maza, a volunteer, traveled to Louisiana and the panhandle of Florida to see firsthand the situation on the ground at the spill.

    The trip was made with the intention of making contacts, visiting the BP Command Center in Houma, La., and taking pictures of the affected area. Communication in the area was not productive, since it seems the local news is not covering the disaster in detail. The people we talked with had very little information regarding the spill and at times the information supplied was not accurate.

    Attempts were made to speak with Coast Guard personnel in restaurants and other places we encountered them, but the response was that no information would be given and that we should contact the Coast Guard Command Center.

    At the gate of the BP Command Center we were stopped by security and given a printed sheet of paper with phone numbers to contact. When I called from my cell phone (STW™ cell phone) the operator who answered the phone knew who I was and that the number was registered to STW™. She also knew that we had filled out a form with BP offering our services. She responded that BP would contact us if they needed our services.

    The oiled beaches were closed by local police and no access was possible. Beaches that had already been cleaned of oil were open and we were able to take some pictures of personnel decontamination stations and some residual oil left behind. Evidence of heavy oiling of the area was observed by the number of 40’ dumpsters located along the main road of Grand Isle. These dumpsters were covered and secured so that we could not look inside.

    We traveled to the very tip of Grand Isle, to the Grand Isle State Park and paid $1 per person to enter the park. No one was on the beach but us and two fishermen on the pier. We were able to go out on the pier and the observation tower and take pictures of an area that had been previously oiled and cleaned. It was obvious that heavy oil had reached the beach by the number of clean-up stations and the staging of a large BP operation center. While taking pictures there we were approached by a BP employee who was returning with a crew, and he informed us that BP did not want pictures taken of their operations. Later while talking to the locals, we were informed that there is a $10,000 fine per picture being assessed to violators.

    On the return trip, we stopped at Destin and Pensacola Beach and there were people on the beaches but not as many as would be in the peak of the season. A clean-up crew of about a dozen was taking turns walking the beach in hazard protection suits looking for tar balls. We followed closely for about an hour to see if any were found.There were no tar balls on the beach.

    The extensive use of oil dispersant has caused most of the oil to drop to the bottom of the Gulf killing everything at the bottom which is the beginning of the food chain. It would have been less harmful to the ecosystems if the oil would have been collected from the surface or the shore; but for BP, out of sight means out of mind, less expense, and less bad publicity.

    In conclusion, our trip turned out to be different than what we expected in that BP and the government are making sure that only the information they want gets out to the public. I felt as if the people of the area were under fear of huge fines if intervening or getting near anything that had to do with the spill.

    STW™ Bioremediation White Paper

    The potential for bioremedial activities of microorganisms in polluted marine sediments is the fundamental approach that must be considered to cost effectively restore the marine ecosystem. The Horizon oil spill is a disaster that could be greatly mitigated with the proper use of bioremediation techniques. The ocean and coastal areas are excellent arenas for the use of bioremediation. Trillions of hungry, gluttonous microbes can economically devour the contamination in the beaches and marches if the proper conditions are maintained after the addition of effective acclimated microorganisms.

    Microorganisms specifically acclimated to degrade crude oil breaks down the carbon chains and use it as food until the contaminant is totally eliminated; when the food source is finished, the microbes die. Bioremediation has been shown to be effective in both the Exxon Valdez spill and the Gulf War cleanup [a]. Application of bioremediation and effective treatment methods are well documented in the literature.

    Chemical analysis before, during, and after application of bioremediation techniques are required to monitor the removal of toxins. Total petroleum hydrocarbons (TPH), and concentrations of selected polynuclear aromatic hydrocarbons (PAHs) are used for technical and practical reasons:

    (1) The simple gravimetric measurement of TPH gives an estimate of all hydrocarbon compounds that may comprise residual oil. This method also includes the co-extraction of material that is not derived from petroleum such: as plant lipid material and waxes. At higher concentrations, the influence of non-petroleum products is not significant.

    (2) The measurement of PAHs is singled out as a class of compounds of concern because they have been linked to acute and chronic toxicological effects. The distribution of individual PAH compounds gives insight into oil weathering or biologically mediated transformation. Quantitative measurement of PAHs is performed by gas chromatography and mass spectrometry (GC/MS). The results of the PAHs analysis can be used by both the biology team and the geology team for information on weathering, source fingerprinting, and persistence. Samples of both sediments and bio-tissue extractions are indicators of PAHs contamination. Detailed chemical analysis is required to confirm the presence of oil and differentiate it among the types of hydrocarbons detected in a monitoring study. Aromatic hydrocarbons are useful in differentiating crude petroleum from combustion byproducts. For instance, crude oil is characterized by PAHs composed primarily of 1-, 2-, and 3- ring aromatic compounds while PAHs compounds resulting from incomplete combustion are characterized by 3-, 4-, and 5- ring aromatic compounds. The ability of distinguishing between background aromatic hydrocarbons derived from natural events, such as fires, and residual oil pollution is achieved through the sensitivity permitted by GC/MS. The following list represents target compounds that should be assessed using GC/MS.

    alkanes
    (nC-10 through nC-31)
    decalin
    C-1 decalin
    C-2 decalin
    C-3 decalin
    naphthalene
    C-1 naphthalenes
    C-2 naphthalene
    C-3 naphthalenes
    C-4 naphthalenes
    fluorene
    C-1 fluorenes
    C-2 fluorenes
    C-3 fluorenes
    dibenzothiophene
    C-1 dibenzothiophenes
    C-2 dibenzothiophenes
    C-3 dibenzothiophenesphenanthrene
    C-1 phenanthrenes
    C-2 phenanthrenes
    C-3 phenanthrenes
    naphthobenzothiophene
    C-1 naphthobenzothiophenes
    C-2 naphthobenzothiophenes
    C-3 naphthobenzothiophenes
    fluoranthrene/pyrene
    C-1 pyrenes
    C-2 pyrenes
    chrysene
    C-1 chrysenes
    C-2 chrysenes
    benzo(b)fluoranthene
    benzo(k)fluoranthene
    benzo(e)pyrene
    benzo(a)pyrene
    perylene
    indeno(1,2,3-cd)pyrene
    dibenzo(a,h)anthracene
    benzo(g,h,i)perylene
    hopanes (191 family)
    sterenes (217 family)

     
     
     

    Processes which affect the fate of oil released into an aquatic environment include: evaporation, dissolution, emulsification, absorption, photochemical, and microbial action. The rate at which these processes occur is controlled by the chemical composition and physical characteristics of the oil and the presence or absence of sufficient microorganisms along with the proper conditions for bioremediation to occur. Reduction in costs up to 90% can be achieved without great disruption of the natural habitat. 60% faster recovery of the bio-systems can be expected compared to conventional methods. All attempts should be made, if possible, to guard from damage or disruption of the natural habitat on beaches and marches during the initial coarse removal of heavy oil contamination. Ecosystems physically disrupted have delayed recoveries. Preliminary feasibility studies are usually not necessary unless the product has not been previously tested for efficacy. Products exist in the market which contains surfactants in addition to microbes that facilitate the dissolution of the oil from the substrate making it more available for the microbes to consume. In situ bioremediation studies are easily implemented on a contaminated beach and yield PAHs analysis results in a short period of time. The PAHs values, before and after biological treatment, can be compared to an adjacent untreated (control) area of the beach. These in situ studies have real visual and scientific verifiable impact on the benefits of bioremediation as a valuable tool to restore ecosystems after disasters such as the Horizon Oil spill.

    © Frank Ramos, Save the Water, Inc.

    [a] N. M. Fayad, et al., Effectiveness of a Bioremediation Product in Degrading the Oil Spilled in the 1991 Arabian Gulf War, 49 Bull. Environ. Contam. Toxicol. 787 (1992); P. H. Pritchard, et al., Oil Spill Bioremediation: Experiences, Lessons and Results from the Exxon Valdes Oil Spill in Alaska, 3 Biodeg. 15 (1992).
    [b] NOAA Technical Memorandum NOS ORCA 114, 1997, Integrating Physical and Biological Studies of Recovery from the Exxon Valdez Oil Spill.

    STW™ US Coast Guard White Paper

    STW™ US Coast Guard White Paper

    Save the Water™, Inc. POC: Frank Ramos (Contracts/Technical)
    500 S.W. 69 Terrace frankramos@savethewater.org
    Pembroke Pines, Fl 33023 Telephone: (786) 417-7000
    Oil Spill Damage Assessment and Restoration – Technical Proposal HSCG32-10-R-R00019
    Section A: Technical Approach – During an oil spill and subsequent reclamation of bio systems, detailed chemical analysis is essential to respond to questions that will arise. Source, toxicity, persistence in the environment, product characteristics initially and after weathering, etc., are a few of the questions that must be answered to track surface restoration technologies.
    Chemistry is an important component of the activities that the Save the Water™ (STW™) Laboratory is engaged in to fulfill its mission to conduct water research to identify toxic chemicals harmful to humans, animals and the environment and to find methods to eliminate the toxins and improve the quality of water. Chemical analysis of the oil entering the environment and its many chemical transformations through reaction with man-made treatments and biological degradation dictates that a thorough chemical study be conducted using the latest techniques in analytical chemistry. In many cases, measurements can be made to the parts per trillion ranges which are very helpful in identifying toxins in bio tissues.
    STW™ proposes to use gas chromatography and mass spectrometry (GC/MS), which is the ideal equipment for detecting and characterizing polycyclic aromatic hydrocarbons (PAH). Crude oil contains a significant amount of PAHs which are considered carcinogenic, mutagenic, and teratogenic. In addition, our laboratory is equipped with inductively coupled plasma (ICP), high-performance liquid chromatography (HPLC), and the scientific personnel required. The STW™ Laboratory will be able to perform tests on oil and its derivatives on beach substrate, contaminated water, and bio-flesh extractions to very sensitive levels.
    The local economy of the affected area will suffer the lasting effects of PAH contamination.
    Decades later, after the horrifying effects of birds covered with oil are forgotten, the PAHs below the surface of the mangroves and the beach will be affecting the food chain of microorganisms and the economic development of the area. The service provided by the STW™ PAH tracing study will help all coastal areas in assessing the risks associated with an oil spill and its economic impact. STW™ proposes to study both the physical and biological changes in sites that were contaminated with petroleum and subsequently treated during cleanup. The study will focus on two specific purposes; 1) to evaluate the effects of both oil and clean up on the physical and biological recovery of the shorelines, and 2) evaluation of the physical substrate or other habitat characteristics that will be appropriate for biological communities’ recovery.
    A multidisciplinary approach is required rather than a series of isolated studies. Chemical sampling is an integral part of geomorphological and biological studies constitute the major components of the monitoring effort. Thus this study will link research findings from all three disciplines.
    The objective of this study is to monitor the persistence of crude petroleum contamination from the Horizon Deep Water Spill, to characterize the chemical composition of oil residues, and to provide information for mapping the degree and distribution of shoreline contamination.
    Different shoreline types are affected differently by oil spills and basic questions arise which include:
    • How long will the oil that penetrated into the beach substrate persist in the environment?
    • How long will it take shorelines modified by washing or berm relocation to return to their original physical configurations?
    • What improvements can be made on our understanding concerning which shorelines are more sensitive to petroleum contamination and/or treatment effects?
    The type of crude petroleum spilled greatly affects its physical behavior, persistence, fate, and effects on biological communities. As a result, chemical analysis of oil residues is critical to understanding both the fate and the effects of spilled petroleum in the environment. It is also important to track how the oil changes as it weathers over space and time. For example, emulsified oil that strands on shore has very different physical properties and behavior, compared to fresh liquid oil. Fresh oil residues are more amiable to biodegradation than emulsified oil.
    A similar study was performed after the Exxon Valdez Oil Spill in 1989. We hope that a cooperative effort can be established to the advantage of the environment and knowledge of the impact for science and STW™. Save the Water™ is a nonprofit organization located in Southeast Florida with easy access to the affected areas.
    Section B: Rough Order of Magnitude (ROM) Cost
    Start up costs: $52,000.00. Initial mobilization, transportation, and lodging for on the ground personnel, sampling, supplies, managerial costs, miscellaneous.
    Per month costs to operate: $97,000.00 (includes Scientists, Technicians, Research assistants, Accountant, Management, Equipment leases, Supplies, Overhead)

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    Water contamination education: Fracking defined – Animated and illustrated fracking news – Slickwater fracking, the technique now known for being so cheap yet so controversial.

     Horizontal drilling, hydraulic fracturing, and shale gas have received a ton of press lately Slickwater fracking the technique illustrated  Volume 3


    Slickwater fracking the technique illustrated Save the water current post

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     Horizontal drilling, hydraulic fracturing, and shale gas have received a ton of press lately,  Slickwater fracking, the technique illustrated

     

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     Horizontal drilling, hydraulic fracturing, and shale gas have received a ton of press lately, Drinking water contamination news


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    Fracking slickwater fracking illustrated

    Animated fracking news-Slickwater fracking.

    This is the technological breakthrough that’s making people wildly bullish on America

    Written by Rob Wile @ Business Insider/ Follow Rob Wile on Twitter.* Copyright © 2012 Business Insider, Inc.

    This weekend, we told the story of three bears who are all bullish on America for one reason: Domestic oil and natural gas. In particular, Hugh Hendry fund manager for Scottish group Eclectica Asset Management, cited “the momentous nature of recent advances in shale oil and gas extraction.”

    So what are these great breakthroughs?

    As it turns out, the three great advances in shale resource extraction occurred more than a decade ago, according to Dan Steward, a geologist with Republic Energy and a former Vice President of Mitchell Energy.

    The first was horizontal well drilling, which infinitely expanded the potential uses of fracking (which has actually been around since the 1949*). Here’s an animation showing exactly what that looks like:

    The first commercially viable horizontal drills had already been executed in the 1980s.

    But it was not until the late ’90s that mapping technology was created that could determine where fracking would prove most successful.

    Microseismic technology (which were originally used to detect seismic activity around mines) involves lowering detectors into a listening well near a fracked well.

    Once the well has been drilled, the seismic devices pick up the noise of where the rocks are breaking, and triangulates the sounds to map out the rest of the play.

    Here’s an equally nifty animation that demonstrates microseismic mapping.

    The final development was the advent of slickwater fracking, the technique now known for being so cheap, yet so controversial.

    Slickwater fracks involve adding chemicals known as “friction reducers” to water to allow for more efficient gas extraction.According to Halliburton and Forest Oil Corp, slickwater fracks allow fluid to be pumped down the well-bore as fast as 100 barrels per minute. Without using slickwater the top speed of pumping is around 60 bbl/min. It also enables extraction in highly pressurized, deeper shales.

    In 1997, Mitchell Energy executed the first slickwater frack (.pdf). Steward says it cut down the cost of drilling a well from $375,000 to $85,000.

    The ensuing “natural gas revolution” has been more the result of revision after revision of potentially recoverable resources. For example, in 1999, a study estimated 8.4 trillion cubic feet of natural gas were recoverable in the mid-Atlantic Marcellus Shale. By 2006, that had been revised upward to 31.4. (Some some now argue we have reached a tipping point where has caused recoverability estimates to be revised back downward.)

    Here’s how that evolution has played out, according to data from Drilling Info:

    So the next time you read something about new innovations in shale extraction, remember this timeline, from Steward:

    “By the year 2000, Mitchell Energy had proven shale as a workable and viable. The energy industry recognized it, but financial markets didn’t recognize until 2002, and politicians only realized it in 2006.”

    It is these decade-old breakthroughs that have resulted in those cheap prices you keep hearing about.

    *Update June 6, 2012: The article originally stated fracking has been around since the 1920s — this should have referred to slanted drilling — a precursor to horizontal drilling — first recorded in 1929. Read more @ Business Insider, Inc

    Further reading:

    Slickwater / Fracking historical perspective

    By Theodore Gilliland, 04/19/2011
    Horizontal drilling, hydraulic fracturing, and shale gas have received a ton of press lately. But what impacts do these unconventional techniques have on energy markets?
    Neither hydraulic fracturing (fracking) nor horizontal drilling are new technologies—the first horizontal well was drilled in 1929 and Halliburton developed fracking in 1949.Shale gas extraction is even older—the first commercial well was drilled in 1821. However, when horizontal drilling and fracking were combined to drill in Texas’ Barnett Shale region in 2003, a natural gas boom was born. In the last decade, shale gas production has increased 14-fold.

    Exhibit 1: Historical Milestones in Unconventional Gas Drilling

    Fracking History

    Definitions by Wikimarcellus

    Slickwater fracking

    Slickwater or slick water fracturing is a method or system of hydro-fracturing which involves adding chemicals to water to increase the fluid flow. Fluid can be pumped down the well-bore as fast as 100 bbl/min. to fracture the shale. Without using slickwater the top speed of pumping is around 60 bbl/min.

    The process reportedly involves injecting friction reducers, usually a a polyacrylamide. Biocides, surfactants and scale inhibitors can also be in the fluid. Friction reducers speed the mixture. Biocides such as bromine prevent organisms from clogging the fissures and sliming things up downhole. Surfactants keep the sand suspended. Methanol and naphthalene can be used for biocides. Hydrochloric acid and ethylene glycol may be utilized as scale inhibitors. Butanol and ethylene glycol monobutyl ether (2-BE) are used in surfactants. Slickwater typically uses more water than earlier fracturing methods–between one and five million gallons per fracing operation.

    Other chemical compounds sometimes used include benzene, chromium and a host of others. Many of these are known to be toxic and have raised widespread concern about potential water contamination. This is especially true when the wells recieving slickwater hydro-fracturing are located near aquifers that are being tapped into for local drinking water. However, reports of actual drinking water contamination appear either very scarce or else non-existent. Hydro-fracturing activity is heavily regulated by state agencies.

    In summary, slickwater is a water-based fluid and proppant combination that has low-viscosity. Slickwater fracturing was first used in the Barnett shale. Mitchell Energy introduced the very first slickwater frac that utilized 800,000 gal. of water and 200,000 lbs. of sand as proppant. It is typically used in highly-pressurized, deeper shales, while fracturing fluids using nitrogen foam are more common in more shallow shales and those that have lower reservoir pressure.

    What is proppant?

    Proppant is porous material such as sand or ceramic beads that are used to prevent newly created fissures and fractures in the shale rock from closing up once it has been hydro-fractured.

    A typical hydro-fractured well uses between 300,000 and 500,000 lbs. of proppant.

    The objective of hydro-fracturing is to enhance the deliverability of trapped gas by making pathways for the flow of natural gas and other hydrocarbons from the shale reservoir to the wellbore. Two chief factors that influence the flow of gas are permeability and proppant.

    Stokes’ law can be used to define four variables that affect proppant settling velocity in a column of water:

    1. fluid specific gravity
    2. fluid viscosity
    3. proppant size
    4. proppant specific gravity

    The cost of hydro-fracturing can be minimized by by reducing frac fluid viscosity. According to Stokes law, reducing the particle (proppant) size in half cuts the settling rate by a factor of four. However, particle size is also proportional to the conductivity of a proppant pack. Hence, in designing a fracing plan these factors must be weighed against each other in order to optimize the flow of gas from the shale reservoir.

    Although naturally occurring sand is frequently utilized as proppant, specially engineered man-made proppants can be used too such as resin-coated sand or high-strength ceramic materials like sintered bauxite. Materials are carefully selected for size and sphericity to provide the most efficient conduit for production of gas and other hydrocarbons from reservoir to wellbore.

    There are three main types of proppant that are in use in hydro-fracturing. Listed in order of their unit cost, these include:

    • sand
    • sand coated with resin
    • ceramic proppant

    The higher initial cost of ceramic proppant over sand may be justified by higher returns on investment in terms of greater well production rates and total overall recovery of oil and gas from the well. Higher production rates result from the greater strength of ceramic proppant and its more uniform shape and size.

    Production engineers use fracture design models as a guide to optimizing fracturing by comparing treatment size versus fracture half-length. The purpose is to design a fracture stimulation plan that optimizes productivity. The lower the permeability of a reservoir the more fracture length determines the effectiveness of the stimulation. However, unless the fractures can be sustained unpropped, that is, unless the fracture length or height created by hydro-fracturing has residual conductivity without propping, it is a waste of fluid. That can reduce the return on investment of hydro-fracturing a well or even turn it into a loss situation.

    Facts: Ten scariest chemicals used in hydraulic fracking

     The following is courtousy of Michael Kelley | Mar. 16, 2012, 1:35 PM

    Methanol

    MethanolFlickr/prizepony
    Methanol appeared most often in hydraulic fracturing products (in terms of the number of compounds containing the chemical).
    Found in antifreeze, paint solvent and vehicle fuel.
    Vapors can cause eye irritation, headache and fatigue, and in high enough doses can be fatal. Swallowing may cause eye damage or death.
     
     

    BTEX compounds

    BTEX compoundsFlcikr/arimoore
    The BTEX compounds – benzene, toluene, xylene, and ethylbenzene – are listed as hazardous air pollutants in the Clean Air Act and contaminents in the Safe Drinking Water Act.
    Benzene, commonly found in gasoline, is also a known human carcinogen. Long time exposure can cause cancer, bone marrow failure, or leukemia. Short term effects include dizziness, weakness, headache, breathlessness, chest constriction, nausea, and vomiting. Toluene, ethylbenzene, and xylenes have harmful effects on the central nervous system. The hydraulic fracturing companies injected 11.4 million gallons of products containing at least one BTEX chemical between 2005 and 2009.

    Diesel fuel

    Diesel fuelA carcinogen listed as a hazardous air pollutant under the Clean Air Act and a contaminant in the Safe Drinking Water Act.
    In its 2004 report, the EPA stated that the “use of diesel fuel in fracturing fluids poses the greatest threat” to underground sources of drinking water.
    Hydraulic fracturing companies injected more than 30 million gallons of diesel fuel or hydraulic fracturing fluids containing diesel fuel in wells in 19 states.
    Diesel fuel contains toxic constituents, including BTEX compounds. Contact with skin may cause redness, itching, burning, severe skin damage and cancer. (Kerosene is also used. Found in jet and rocket fuel, the vapor can cause irritation of the eyes and nose, and ingestion can be fatal. Chronic exposure may cause drowsiness, convulsions, coma or death.)

    Lead

    LeadFlickr/matthileo
    A carcinogen found in paint, building construction materials and roofing joints.
    It is listed as a hazardous air pollutant in the Clean Air Act and a contaminant in the Safe Drinking Water Act.
    Lead is particularly harmful to children’s neurological development. It also can cause reproductive problems, high blood pressure, and nerve disorders in adults.
    One of the hydraulic fracturing companies used 780 gallons of a product containing lead between 2005 and 2009.

    Hydrogen fluoride

    Hydrogen fluorideFlickr/Molly Des Jardin
    Found in rust removers, aluminum brighteners and heavy duty cleaners.
    Listed as a hazardous air pollutant in the Clean Air Act.
    Fumes are highly irritating, corrosive, and poisonous. Repeated ingestion over time can lead to hardening of the bones, and contact with liquid can produce severe burns. A lethal dose is 1.5 grams.
    Absorption of substantial amounts of hydrogen fluoride by any route may be fatal.
    One of the hydraulic fracturing companies used 67,222 gallons of two products containing hydrogen fluoride in 2008 and 2009.

    Naphthalene

    NaphthaleneFlickr/CraftyGoat
    A carcinogen found in mothballs.
    Listed as a hazardous air pollutant in the Clean Air Act.
    Inhalation can cause respiratory tract irritation, nausea, vomiting, abdominal pain, fever or death.
     
     
     

    Sulfuric acid

    Sulfuric acidFlickr/yetanotherdave
    A carcinogen found in lead-acid batteries for cars.
    Corrosive to all body tissues. Inhalation may cause serious lung damage and contact with eyes can lead to a total loss of vision. The lethal dose is between 1 teaspoonful and one-half ounce.
     
     
     

    Crystalline silica

    Crystalline silicaSource: ProPublica
    A carcinogen found in concrete, brick mortar and construction sands.
    Dust is harmful if inhaled repeatedly over a long period of time and can lead to silicosis or cancer.
     
     
     
     

    Formaldehyde

    FormaldehydeFlickr/Stadtkatze
    A carcinogen found in embalming agents for human or animal remains.
    Ingestion of even one ounce of liquid can cause death. Exposure over a long period of time can cause lung damage and reproductive problems in women.
     
     
     

    Unknown chemicals

    Unknown chemicalsFlickr/SoulRider.222
    “Many of the hydraulic fracturing fluids contain chemical components that are listed as ‘proprietary’ or ‘trade secret.’ The companies used 94 million gallons of 279 products that contained at least one chemical or component that the manufacturers deemed proprietary or a trade secret. In many instances, the oil and gas service companies were unable to identify these ‘proprietary’ chemicals,suggesting that the companies are injecting fluids containing chemicals that they themselves cannot identify.”

     

    Facts: List of chemicals now known to be used in fracking

     
    Multiple names for the same chemical can also leave you with the impression that there are more chemicals than actually exist. If you search the National Institute of Standards and Technology (NIST) ‡ website the alternate names of chemicals are listed.

    Back To Top

    Chemical Name CAS Chemical Purpose Product Function
    Hydrochloric Acid 007647-01-0 Helps dissolve minerals and initiate cracks in the rock Acid
    Glutaraldehyde 000111-30-8 Eliminates bacteria in the water that produces corrosive by-products Biocide
    Quaternary Ammonium Chloride 012125-02-9 Eliminates bacteria in the water that produces corrosive by-products Biocide
    Quaternary Ammonium Chloride 061789-71-1 Eliminates bacteria in the water that produces corrosive by-products Biocide
    Tetrakis Hydroxymethyl-Phosphonium Sulfate 055566-30-8 Eliminates bacteria in the water that produces corrosive by-products Biocide
    Ammonium Persulfate 007727-54-0 Allows a delayed break down of the gel Breaker
    Sodium Chloride 007647-14-5 Product Stabilizer Breaker
    Magnesium Peroxide 014452-57-4 Allows a delayed break down the gel Breaker
    Magnesium Oxide 001309-48-4 Allows a delayed break down the gel Breaker
    Calcium Chloride 010043-52-4 Product Stabilizer Breaker
    Choline Chloride 000067-48-1 Prevents clays from swelling or shifting Clay Stabilizer
    Tetramethyl ammonium chloride 000075-57-0 Prevents clays from swelling or shifting Clay Stabilizer
    Sodium Chloride 007647-14-5 Prevents clays from swelling or shifting Clay Stabilizer
    Isopropanol 000067-63-0 Product stabilizer and / or winterizing agent Corrosion Inhibitor
    Methanol 000067-56-1 Product stabilizer and / or winterizing agent Corrosion Inhibitor
    Formic Acid 000064-18-6 Prevents the corrosion of the pipe Corrosion Inhibitor
    Acetaldehyde 000075-07-0 Prevents the corrosion of the pipe Corrosion Inhibitor
    Petroleum Distillate 064741-85-1 Carrier fluid for borate or zirconate crosslinker Crosslinker
    Hydrotreated Light Petroleum Distillate 064742-47-8 Carrier fluid for borate or zirconate crosslinker Crosslinker
    Potassium Metaborate 013709-94-9 Maintains fluid viscosity as temperature increases Crosslinker
    Triethanolamine Zirconate 101033-44-7 Maintains fluid viscosity as temperature increases Crosslinker
    Sodium Tetraborate 001303-96-4 Maintains fluid viscosity as temperature increases Crosslinker
    Boric Acid 001333-73-9 Maintains fluid viscosity as temperature increases Crosslinker
    Zirconium Complex 113184-20-6 Maintains fluid viscosity as temperature increases Crosslinker
    Borate Salts N/A Maintains fluid viscosity as temperature increases Crosslinker
    Ethylene Glycol 000107-21-1 Product stabilizer and / or winterizing agent. Crosslinker
    Methanol 000067-56-1 Product stabilizer and / or winterizing agent. Crosslinker
    Polyacrylamide 009003-05-8 “Slicks” the water to minimize friction Friction Reducer
    Petroleum Distillate 064741-85-1 Carrier fluid for polyacrylamide friction reducer Friction Reducer
    Hydrotreated Light Petroleum Distillate 064742-47-8 Carrier fluid for polyacrylamide friction reducer Friction Reducer
    Methanol 000067-56-1 Product stabilizer and / or winterizing agent. Friction Reducer
    Ethylene Glycol 000107-21-1 Product stabilizer and / or winterizing agent. Friction Reducer
    Guar Gum 009000-30-0 Thickens the water in order to suspend the sand Gelling Agent
    Petroleum Distillate 064741-85-1 Carrier fluid for guar gum in liquid gels Gelling Agent
    Hydrotreated Light Petroleum Distillate 064742-47-8 Carrier fluid for guar gum in liquid gels Gelling Agent
    Methanol 000067-56-1 Product stabilizer and / or winterizing agent. Gelling Agent
    Polysaccharide Blend 068130-15-4 Thickens the water in order to suspend the sand Gelling Agent
    Ethylene Glycol 000107-21-1 Product stabilizer and / or winterizing agent. Gelling Agent
    Citric Acid 000077-92-9 Prevents precipitation of metal oxides Iron Control
    Acetic Acid 000064-19-7 Prevents precipitation of metal oxides Iron Control
    Thioglycolic Acid 000068-11-1 Prevents precipitation of metal oxides Iron Control
    Sodium Erythorbate 006381-77-7 Prevents precipitation of metal oxides Iron Control
    Lauryl Sulfate 000151-21-3 Used to prevent the formation of emulsions in the fracture fluid Non-Emulsifier
    Isopropanol 000067-63-0 Product stabilizer and / or winterizing agent. Non-Emulsifier
    Ethylene Glycol 000107-21-1 Product stabilizer and / or winterizing agent. Non-Emulsifier
    Sodium Hydroxide 001310-73-2 Adjusts the pH of fluid to maintains the effectiveness of other components, such as crosslinkers pH Adjusting Agent
    Potassium Hydroxide 001310-58-3 Adjusts the pH of fluid to maintains the effectiveness of other components, such as crosslinkers pH Adjusting Agent
    Acetic Acid 000064-19-7 Adjusts the pH of fluid to maintains the effectiveness of other components, such as crosslinkers pH Adjusting Agent
    Sodium Carbonate 000497-19-8 Adjusts the pH of fluid to maintains the effectiveness of other components, such as crosslinkers pH Adjusting Agent
    Potassium Carbonate 000584-08-7 Adjusts the pH of fluid to maintains the effectiveness of other components, such as crosslinkers pH Adjusting Agent
    Copolymer of Acrylamide and Sodium Acrylate 025987-30-8 Prevents scale deposits in the pipe Scale Inhibitor
    Sodium Polycarboxylate N/A Prevents scale deposits in the pipe Scale Inhibitor
    Phosphonic Acid Salt N/A Prevents scale deposits in the pipe Scale Inhibitor
    Lauryl Sulfate 000151-21-3 Used to increase the viscosity of the fracture fluid Surfactant
    Ethanol 000064-17-5 Product stabilizer and / or winterizing agent. Surfactant
    Naphthalene 000091-20-3 Carrier fluid for the active surfactant ingredients Surfactant
    Methanol 000067-56-1 Product stabilizer and / or winterizing agent. Surfactant
    Isopropyl Alcohol 000067-63-0 Product stabilizer and / or winterizing agent. Surfactant
    2-Butoxyethanol 000111-76-2 Product stabilizer Surfactant

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    Fracking
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  • Whats Fracking All About? Part 2
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  • What are some of the known water pollutants?
  • What Are Some Facts About Water? Over 100 Facts You May Not Know.
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